Mono- and dinuclear Pd(II) complexes of different salicylaldimine ligands as catalysts of transfer hydrogenation of nitrobenzene with cyclohexene and Suzuki-Miyaura coupling reactions

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridKilic, Ahmet/0000-0001-9073-4339
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridyilmaz, ismail/0000-0002-5046-7456
dc.authoridDURGUN, Mustafa/0000-0003-3012-7582
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidKilic, Ahmet/B-8904-2012
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidyilmaz, ismail/N-6592-2014
dc.authorwosidDURGUN, Mustafa/AAG-4570-2019
dc.contributor.authorTas, E.
dc.contributor.authorKilic, A.
dc.contributor.authorDurgun, M.
dc.contributor.authorYilmaz, I.
dc.contributor.authorOzdemir, I.
dc.contributor.authorGurbuz, N.
dc.date.accessioned2024-08-04T20:31:06Z
dc.date.available2024-08-04T20:31:06Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, the synthesis, spectroscopic, catalytic, and electrochemical properties of salicylaldimine Schiff-base ligands (L-n) and their dinuclear Pd(II) complexes for L-1 and L-2 ligands with mononuclear Pd(II) complexes for L-3 and L-4 ligands were investigated. The ligands and their mono- or dinuclear Pd(II) complexes were characterized by FT-IR, UV-Vis, H-1 NMR and elemental analysis, as well as through magnetic susceptibility and spectroelectrochemical techniques. The catalytic studies showed that the introduction of tert butyl groups on the salicyl ring of the molecules increased the catalytic activity towards hydrogenation of nitrobenzene and cyclohexene in DMF at 25 and 45 degrees C. It was also observed that the steric hindered mono- and dinuclear Pd( II) complexes were thermally stable complexes and were not sensitive to air or the moisture. The complexes were easily prepared from cheap materials that could be used as versatile and efficient catalysts for different C-C coupling reactions (Suzuki-Miyaura reactions). (C) 2008 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK [106T085]en_US
dc.description.sponsorshipThis work was supported, in part, by the Technological and Scientific Research Council of Turkey TUBITAK (TBAG Project No: 106T085).en_US
dc.identifier.doi10.1016/j.jorganchem.2008.11.021
dc.identifier.endpage454en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-58149520152en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage446en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2008.11.021
dc.identifier.urihttps://hdl.handle.net/11616/94733
dc.identifier.volume694en_US
dc.identifier.wosWOS:000262608500018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectSynthesisen_US
dc.subjectMono- and dinuclear Pd(II) complexesen_US
dc.subjectHydrogenationen_US
dc.subjectSuzuki coupling reactionsen_US
dc.subjectElectrochemistryen_US
dc.subjectSpectroelectrochemistryen_US
dc.titleMono- and dinuclear Pd(II) complexes of different salicylaldimine ligands as catalysts of transfer hydrogenation of nitrobenzene with cyclohexene and Suzuki-Miyaura coupling reactionsen_US
dc.typeArticleen_US

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