Regioselective allylic alkylation and etherification catalyzed by in situ generated N-heterocyclic carbene ruthenium complexes

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dc.authoridRENAUD, Jean-Luc/0000-0001-8757-9622
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidRENAUD, Jean-Luc/JAX-2908-2023
dc.authorwosidRENAUD, Jean-Luc/ABD-6660-2020
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.contributor.authorGürbüz, N
dc.contributor.authorÖzdemir, I
dc.contributor.authorÇetinkaya, B
dc.contributor.authorRenaud, JL
dc.contributor.authorDemerseman, B
dc.contributor.authorBruneau, C
dc.date.accessioned2024-08-04T20:15:07Z
dc.date.available2024-08-04T20:15:07Z
dc.date.issued2006
dc.departmentİnönü Üniversitesien_US
dc.description.abstractBenzimidazolium halides are used for the first time as ligand precursors in ruthenium-catalyzed substitution of allylic carbonates and chlorides by carbon nucleophiles and phenols, respectively. After generation of diaminocarbene species upon deprotonation by tBuOK, their association with [Cp*Ru(MeCN)(3)]PF6 induces a very high regioselectivity in favor of the branched isomers when cinnamyl derivatives are used as starting substrates. They also provide good regioselectivities for the allylation of phenols by unsymmetrical aliphatic allylic substrates such as 3-chloro-4-phenylbut-1-ene, and thus provide a straightforward access to new allylic phenyl ethers. (c) 2005 Elsevier Ltd. All rights reserved.en_US
dc.identifier.doi10.1016/j.tetlet.2005.11.051
dc.identifier.endpage538en_US
dc.identifier.issn0040-4039
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-29144487914en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage535en_US
dc.identifier.urihttps://doi.org/10.1016/j.tetlet.2005.11.051
dc.identifier.urihttps://hdl.handle.net/11616/94189
dc.identifier.volume47en_US
dc.identifier.wosWOS:000234624600030en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedron Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAsymmetric Hydrogenationen_US
dc.subjectAlkene Metathesisen_US
dc.subjectSubstitutionen_US
dc.subjectDerivativesen_US
dc.subjectPrecursorsen_US
dc.subjectAminationen_US
dc.subjectLigandsen_US
dc.subjectHalidesen_US
dc.titleRegioselective allylic alkylation and etherification catalyzed by in situ generated N-heterocyclic carbene ruthenium complexesen_US
dc.typeArticleen_US

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