Heterogenization of homogeneous NHC-Pd-pyridine catalysts and investigation of their catalytic activities in Suzuki-Miyaura coupling reactions

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridKünkül, Asım/0000-0002-6080-2588
dc.authoridBoztepe, Cihangir/0000-0001-5019-2010
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.authorwosidBoztepe, Cihangir/H-5877-2018
dc.authorwosidKünkül, Asım/ABG-8608-2020
dc.contributor.authorBoztepe, Cihangir
dc.contributor.authorKunkul, Asim
dc.contributor.authorYasar, Sedat
dc.contributor.authorGurbuz, Nevin
dc.date.accessioned2024-08-04T20:45:21Z
dc.date.available2024-08-04T20:45:21Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew generation, novel, environmentally safe polymeric heterogeneous catalysts which included catalytically active NHC-Pd-pyridine complexes were prepared by radical polymerization of NHC-Pd-pyridine complexes with Acrylamide (AAm) and 2-acrylamido-2-methylpropane sulfonic acid (AMPS) monomers in the presence of N,N'-methylenebisacrylamide (MBA) crosslinker. Structural characterization of NHCPd-pyridine complexes was conducted by using NMR, FT-IR while the structural characterization of crosslinked polymeric catalyst systems was made by using FT-IR, SEM, SEM-EDX, TEM and TGA analysis techniques. The synthesized polymer-based NHC-Pd-pyridine catalysts showed good catalytic activity for Suzuki reaction of aryl bromides with phenylboronic acid in aqueous media. They exhibited good stability and they could be reused at least five times without remarkable loss of catalytic activity. (C) 2018 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2018.07.004
dc.identifier.endpage134en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85051015364en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage123en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2018.07.004
dc.identifier.urihttps://hdl.handle.net/11616/98414
dc.identifier.volume872en_US
dc.identifier.wosWOS:000443285900015en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectNHC-Pd-pyridineen_US
dc.subjectHydrogelen_US
dc.subjectPolymer-based catalystsen_US
dc.subjectSuzuki-Miyaura reactionsen_US
dc.subjectHeterogeneous catalysten_US
dc.titleHeterogenization of homogeneous NHC-Pd-pyridine catalysts and investigation of their catalytic activities in Suzuki-Miyaura coupling reactionsen_US
dc.typeArticleen_US

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