N-Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N-Heterocyclic Carbene Ligands

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dc.authoridACHARD, Mathieu/0000-0003-0578-9680
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridŞAHİN, Zeynel/0000-0002-7719-7652
dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidACHARD, Mathieu/M-4916-2017
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidŞAHİN, Zeynel/AAN-9585-2021
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.contributor.authorSahin, Zeynel
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.contributor.authorAchard, Mathieu
dc.contributor.authorBruneau, Christian
dc.date.accessioned2024-08-04T20:40:17Z
dc.date.available2024-08-04T20:40:17Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of new benzimidazolium salts and ruthenium(II) complexes containing chelating N-heterocyclic carbenes (NHCs) functionalized with a benzylic group and an acetal group were prepared. All of the synthesized compounds were characterized by elemental analysis and NMR spectroscopy, and the molecular structures of 2c and 2d were determined by X-ray crystallography. All of the,complexes were tested in the alkylation of cyclic amine derivatives with alcohols and showed excellent activity in this reaction. Cyclic amines were alkylated with primary and heteroaromatic alcohols. The Ru-NHC Complexes also catalyzed N,C3-dialkylation of cyclic amines.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey (TUBITAK) [112T303]; Inonu University Research Fund [I.U. B.A.P: 2014/Gudumlu-53]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey (TUBITAK) (112T303) and the Inonu University Research Fund (I.U. B.A.P: 2014/Gudumlu-53).en_US
dc.identifier.doi10.1021/om501066n
dc.identifier.endpage2304en_US
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-84931270334en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage2296en_US
dc.identifier.urihttps://doi.org/10.1021/om501066n
dc.identifier.urihttps://hdl.handle.net/11616/96824
dc.identifier.volume34en_US
dc.identifier.wosWOS:000356841800031en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofOrganometallicsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransition-Metal-Complexesen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectSecondary Alcoholsen_US
dc.subjectBeta-Alkylationen_US
dc.subjectStereodirecting Ligandsen_US
dc.subjectSelective Alkylationen_US
dc.subjectRecyclable Catalysten_US
dc.subjectReductive Aminationen_US
dc.subjectEfficient Catalystsen_US
dc.subjectAlkene Metathesisen_US
dc.titleN-Alkylation and N,C-Dialkylation of Amines with Alcohols in the Presence of Ruthenium Catalysts with Chelating N-Heterocyclic Carbene Ligandsen_US
dc.typeArticleen_US

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