Synthesis of ZSM-5 from modified clinoptilolite and its catalytic activity in alkylation of benzene to ethylbenzene

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dc.authoridKartal, Özlem Esen/0000-0002-7510-5427
dc.authorwosidONAL, ISIK/AAG-6246-2019
dc.authorwosidKartal, Özlem Esen/AAH-1109-2020
dc.contributor.authorKartal, Ozlem Esen
dc.contributor.authorOnal, Isik
dc.date.accessioned2024-08-04T20:30:48Z
dc.date.available2024-08-04T20:30:48Z
dc.date.issued2008
dc.departmentİnönü Üniversitesien_US
dc.description.abstractZSM-5 catalysts were prepared by utilizing clinoptilolite found in Western Anatolia in abundant amounts as a type of natural zeolite. Hydrothermal reaction was conducted with HCl-treated clinoptilolite at 180 degrees C. After characterizing the solid products obtained by this reaction as ZSM-5 by means of XRD, IR, TGA, surface area analyzer, and chemical analysis they were tested as catalysts in benzene alkylation reaction with ethylene leading to ethylbenzene. Catalytic performance of samples prepared in this study was investigated for benzene conversion, ethylbenzene yield, and selectivity. It was found that ZSM-5(A) sample showed performance similar to that of the reference sample (ZSM-5(C)) synthesized by using patented literature information in terms of benzene conversion. When the reaction temperature was increased from 400 to 425 degrees C ethylbenzene yield and selectivity results of ZSM-5(A) sample were improved but coke formation increased. Catalyst test results indicated the possibility of using clinoptilolite as a raw material in the synthesis of ZSM-5 catalyst for alkylation of benzene with ethylene reaction.en_US
dc.identifier.doi10.1080/00986440801907078
dc.identifier.endpage1057en_US
dc.identifier.issn0098-6445
dc.identifier.issue8en_US
dc.identifier.scopus2-s2.0-43149098318en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1043en_US
dc.identifier.urihttps://doi.org/10.1080/00986440801907078
dc.identifier.urihttps://hdl.handle.net/11616/94526
dc.identifier.volume195en_US
dc.identifier.wosWOS:000255301700011en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherTaylor & Francis Incen_US
dc.relation.ispartofChemical Engineering Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectalkylationen_US
dc.subjectcatalysten_US
dc.subjectclinoptiloliteen_US
dc.subjectethylbenzeneen_US
dc.subjectZSM-5en_US
dc.titleSynthesis of ZSM-5 from modified clinoptilolite and its catalytic activity in alkylation of benzene to ethylbenzeneen_US
dc.typeArticleen_US

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