Synthesis of novel 1-alkylimidazoline and 1-alkylbenzimidazole palladium(II) complexes as efficient catalysts for Heck and Suzuki reactions involving arylchlorides
Küçük Resim Yok
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Six palladium(II) complexes of the type [PdCl2(PR3)L], {PR3 = PPh3 or PPhMe2; L = 1-alkyl-2-imidazoline(1) or 1-alkylbenzimidazole(2)} have been prepared by reactions of [PdCl2(PR3)](2). The complexes were characterized by conventional spectroscopic methods and elemental analyses. The incorporation of N-coordinated imidazoline and benzimidazole complexes of palladium(II) gave high catalytic activity in the Suzuki coupling and Heck reaction of aryl bromides and deactivated aryl chloride substrates. (C) 2003 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
palladium, imidazolidine, benzimidazole, Suzuki, Heck
Kaynak
Journal of Molecular Catalysis A-Chemical
WoS Q Değeri
Q2
Scopus Q Değeri
N/A
Cilt
208
Sayı
1-2
