Surface modification of inorganic oxide particles with a carbene complex of palladium: A recyclable catalyst for the Suzuki reaction
Küçük Resim Yok
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer New York LLC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The reaction of 1-(2,4,6-trimethylbenzyl)-3-(propyltriethoxysilane) imidazolidinium chloride, with the Pd(OAc)2 complex proceeded smoothly in DMSO to give the bis[1-(2,4,6-trimethylbenzyl)-3- (propyltriethoxysilane)imidazolidin-2-ylidene]dichloropalladium(II) complex that was grafted onto the surface of amorphous silica. The effects of various factors, such as reaction temperature and time, on the grafting efficiency was evaluated. Inorganic oxide particles that were modified with a carbene complex of palladium(II) were tested for catalytic activity in the Suzuki coupling reaction between phenylboronic acid and several aryl halides © 2004 Plenum Publishing Corporation.
Açıklama
Anahtar Kelimeler
Palladium(II) carbene complex catalyst, Silane coupling, Surface modification, Suzuki reaction
Kaynak
Journal of Inorganic and Organometallic Polymers and Materials
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
14
Sayı
2