Synthesis of nickelocene containing polyimides with low-dielectric constants
Küçük Resim Yok
Tarih
2009
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Polyimides embedding the nickelocene unit were prepared by in situ curing of poly(amic acid) macromolecules with nickelocene, for the molecular-level design of low-dielectric constant (IOW-kappa) materials. The effects of nickelocene on dielectric properties of polyimide are investigated in detail in this study. Nickelocene containing polyimides exhibit a number of desirable properties including low-water absorption and admirable thermal stability. Systematic studies demonstrate that proper insertion of nickelocene into a polyimide backbone can give rise to a reduction in the material's dielectric constant. All composites were subjected to DSC measurements for the purpose of examining microscopic miscibility. DSC thermograms of all composites showed only one T-g from all composition. (C) 2008 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Composite materials, Inorganic materials, Chemical synthesis, Dielectric response, Thermal analysis
Kaynak
Journal of Alloys and Compounds
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
470
Sayı
1-2
