Synthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactions

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authoridJan, Kalsoom/0000-0002-9010-0608
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidHabib, Uzma/IXW-8205-2023
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.contributor.authorNawaz, Zahid
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorZafar, Muhammad Naveed
dc.contributor.authorOzdemir, Namik
dc.contributor.authorHabib, Uzma
dc.contributor.authorJan, Kalsoom
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:50:25Z
dc.date.available2024-08-04T20:50:25Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe goal of our research is to synthesis homogeneous catalysts, for which we take start from two novel precursors of 1-(3-methyloxetane-3-yl)benzimidazole and 5,6-dimethyl-1-((3-methyloxetane3-yl)benzimidazole. A series of ligands containing 1,3-disubstituted benzimidazolium salts were synthesized from the corresponding precursors to form N-heterocyclic carbene (NHC) ligands. Furthermore, four new Pd(NHC)-PEPPSI type complexes were synthesized from these ligands. The structure elucidation of all the synthesized ligands, and complexes was confirmed by various spectroscopic techniques such as NMR, FT-IR. The compounds 1b, 2b, 3a, 3d were confirmed by the X-ray technique. All these complexes were found significantly active as catalysts toward the C-C cross-coupling reaction. (c) 2021 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTuBITAK; Scientific Research Projects Unit of On-dokuz Mays University [PYO.FEN.1906.19.001]; Inonu University Research Fund [Iu-BAP: FBG-2019-1594]en_US
dc.description.sponsorshipThe authors gratefully acknowledged TuBITAK for research funding (Zahid Nawaz-2216 Research Fellowship Programme) . This study was supported by by Scientific Research Projects Unit of On-dokuz Mays University (Project No: PYO.FEN.1906.19.001) and the Inonu University Research Fund (Iu-BAP: FBG-2019-1594) .en_US
dc.identifier.doi10.1016/j.molstruc.2021.130883
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85111007034en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2021.130883
dc.identifier.urihttps://hdl.handle.net/11616/100059
dc.identifier.volume1243en_US
dc.identifier.wosWOS:000687881100001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectPalladium-PEPPSI complexesen_US
dc.subjectSuzuki-Miyaura couplingen_US
dc.subjectMizoroki-Heck couplingen_US
dc.subjectSonogashira couplingen_US
dc.titleSynthesis of new Pd(NHC)-PEPPSI type complexes as catalysts toward C-C cross-coupling reactionsen_US
dc.typeArticleen_US

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