5-Nitrobenzimidazole containing Pd(II) catalyzed C-C cross-coupling reactions: The effect of the N-substituent of the benzimidazole structure on catalyst activity

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridBULDURUN, Kenan/0000-0002-2462-7006
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBULDURUN, Kenan/AAD-5162-2019
dc.contributor.authorBuldurun, Kenan
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:45:59Z
dc.date.available2024-08-04T20:45:59Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA series of Pd(II) complexes (1a-e) were successfully synthesized by reaction of N-substituted 5-nitrobenzimidazole with [PdCl2(CNCH3)(2)] in toluene under argon reflux condition. Their catalytic activity in the Suzuki-Miyaura and Mizoroki-Heck coupling reactions were investigated. All these complexes were characterized by elemental analysis, H-1 NMR, C-13 NMR and IR spectroscopy. The catalytic activities of N-substituted 5-nitrobenzimidazole palladium (II) complexes were screened in Mizoroki-Heck and Suzuki-Miyaura coupling reactions. The reactions were optimized for the most suitable temperature, solvent and base system. The Pd(II) complexes exhibited good catalytic activity at the Mizoroki-Heck reaction. Additionally, the Suzuki-Miyaura showed relatively excellent activity at the coupling reaction. (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molstruc.2019.04.101
dc.identifier.endpage177en_US
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85065816525en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage172en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2019.04.101
dc.identifier.urihttps://hdl.handle.net/11616/98801
dc.identifier.volume1192en_US
dc.identifier.wosWOS:000469236000020en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Bven_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subject5-Nitrobenzimidazoleen_US
dc.subjectCatalytic activityen_US
dc.subjectSuzuki-Miyauraen_US
dc.subjectSpectroscopyen_US
dc.title5-Nitrobenzimidazole containing Pd(II) catalyzed C-C cross-coupling reactions: The effect of the N-substituent of the benzimidazole structure on catalyst activityen_US
dc.typeArticleen_US

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