Design and characterization of amino and chloro functionalized rhombohedral silsesquioxanes
| dc.contributor.author | Gültek, Ahmet | |
| dc.contributor.author | Seçkin, Turgay | |
| dc.contributor.author | Adıgüzel, Halil İbrahim | |
| dc.date.accessioned | 2020-07-01T13:54:34Z | |
| dc.date.available | 2020-07-01T13:54:34Z | |
| dc.date.issued | 2005 | |
| dc.department | İnönü Üniversitesi | en_US |
| dc.description.abstract | Öz: Başlık (İngilizce): Öz (İngilizce): A more rapid and a versatile synthetic approach for the preparation of polyhedral silsesquioxanes (POSS) by hydrolytic condensation of organosilicon monomers in the presence of a Pt catalyst was studied. The structural properties of POSS molecules were determined by X-ray powder diffraction analysis, yielding a rhombohedral unit cell with a = 11,52796A and a = 94,9754° for octaaminopropyl-POSS, and a rhombohedral unit cell with a = 11,51421A, a = 96,7214° for octachloropropyl-POSS. The activation energies were found to be 64.8, and 89.1 kJ/mol for octaaminopropyl-POSS and octachloropropyl-POSS, respectively. The products were also characterized by Fourier transform infrared spectroscopy, 1H and 13C nuclear magnetic resonance, differential thermal analysis, and thermogravimetric analysis | en_US |
| dc.identifier.citation | Ahmet G., TURGAY S., HALİL İBRAHİM A. (2005). Design and characterization of amino and chloro functionalized rhombohedral silsesquioxanes, Turkish Journal of Chemistry, İnönü Üniversitesi, Malatya. | en_US |
| dc.identifier.endpage | 399 | en_US |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.issn | 1303-6130 | |
| dc.identifier.issue | 4 | en_US |
| dc.identifier.startpage | 391 | en_US |
| dc.identifier.trdizinid | 48991 | en_US |
| dc.identifier.uri | https://hdl.handle.net/11616/16280 | |
| dc.identifier.uri | https://search.trdizin.gov.tr/yayin/detay/48991 | |
| dc.identifier.volume | 29 | en_US |
| dc.identifier.wos | WOS:000231602700007 | en_US |
| dc.identifier.wosquality | Q2 | en_US |
| dc.indekslendigikaynak | TR-Dizin | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.language.iso | tr | en_US |
| dc.publisher | Turkish Journal of Chemistry | en_US |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.subject | Mühendislik | en_US |
| dc.subject | Kimya | en_US |
| dc.title | Design and characterization of amino and chloro functionalized rhombohedral silsesquioxanes | en_US |
| dc.type | Article | en_US |
