PALLADIUM/BENZIMIDAZOLIUM SALT CATALYST SYSTEMS AND N-HETEROCYCLIC CARBENE-PALLADIUM(II)-PYRIDINE (PEPPSI) COMPLEXES FOR ANTI-MARKOVNIKOV HYDROAMINATIONS OF STYRENE IN IONIC LIQUID
Küçük Resim Yok
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Pergamon-Elsevier Science Ltd
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
Both in situ prepared Pd-NHC and NHC-Pd-PEPPSI complexes were tested as catalysts in the intermolecular hydroamination reactions between styrene with various anilines in ionic liquid. All of the compounds tested here are catalytically active for the intermolecular hydroamination of styrene with aromatic amines. The anti-Markovnikov addition products were obtained selectively by using 1 mol% of the palladium complex.
Açıklama
Anahtar Kelimeler
Intermolecular Hydroamination, Carbene Complexes, Asymmetric Hydroamination, Coupling Reactions, Alkaline-Earth, Palladium, Ligands, Alkenes, Precatalysts, Vinylarenes
Kaynak
Heterocycles
WoS Q Değeri
Q4
Scopus Q Değeri
Q4
Cilt
98
Sayı
3
