Palladium nanoparticle supported on nitrogen-doped porous carbon: Investigation of structural properties and catalytic activity on Suzuki-Miyaura reactions

Basit Öğe Kaydı
dc.authoridAltin, Serdar/0000-0002-4590-907X
dc.authoridBugday, Nesrin/0000-0002-3882-035X
dc.authoridyasar, sedat/0000-0001-7285-2761
dc.contributor.authorBugday, Nesrin
dc.contributor.authorAltin, Serdar
dc.contributor.authorYasar, Sedat
dc.date.accessioned2024-08-04T20:50:36Z
dc.date.available2024-08-04T20:50:36Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNovel palladium-doped nanoporous carbon composite material obtained via thermolysis of amorphous zeolitic imidazolate framework (aZIF) was synthesized and used as an efficient catalyst on Suzuki-Miyaura cross-coupling reactions of aryl bromides. With this developed catalytic system, the Suzuki-Miyaura cross-coupling reaction was accomplished in aqueous solutions, and biaryls were obtained in good to excellent yields in a short reaction time. The APC-750@Pd catalyst was characterized by Fourier Transform Infrared spectroscopy (FTIR), X-ray Diffraction (XRD), Scanning Electron Eicroscopy (SEM), X-ray Photoelectron Spectroscopy (XPS), Transmission Electron Microscopy (TEM), Thermal Gravimetric Analysis (TGA), Differential Thermal Analysis (DTA), Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Brunauer-Emmett-Teller (BET) analysis tecniques. N-doped porous carbon material (NPC-1000) was synthesized by thermolysis from aZIF. Activated porous carbon material (APC-750) was fabricated via fused at 750 degrees C with KOH from NPC-1000. The APC-750@Pd was obtained as a result of the interaction of APC-750 and PdCl2 in deionized water. The cross-coupling reaction of different aryl bromides with phenylboronic acid was investigated to show the potential of the APC-750@Pd in the Suzuki-Miyaura cross-coupling reactions. The APC-750@Pd catalyst could be recycled at least five times with a 15% loss of catalytic efficiency in this catalytic system.en_US
dc.description.sponsorshipInonu University Research Councilen_US
dc.description.sponsorshipInonu University Research Councilen_US
dc.identifier.doi10.1002/aoc.6403
dc.identifier.issn0268-2605
dc.identifier.issn1099-0739
dc.identifier.issue11en_US
dc.identifier.scopus2-s2.0-85113731495en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1002/aoc.6403
dc.identifier.urihttps://hdl.handle.net/11616/100167
dc.identifier.volume35en_US
dc.identifier.wosWOS:000687462600001en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofApplied Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectamorphous ZIFen_US
dc.subjectC-C bond formationen_US
dc.subjectcross-couplingen_US
dc.subjectMOFen_US
dc.subjectSuzuki-Miyauraen_US
dc.titlePalladium nanoparticle supported on nitrogen-doped porous carbon: Investigation of structural properties and catalytic activity on Suzuki-Miyaura reactionsen_US
dc.typeArticleen_US

Dosyalar

Koleksiyon

WoS İndeksli Yayınlar Koleksiyonu
Scopus İndeksli Yayınlar Koleksiyonu