Cycloheptyl substituted N-heterocyclic carbene PEPPSI-type palladium complexes with different N-coordinated ligands: Involvement in Suzuki-Miyaura reaction

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dc.authoridKarataş, Mert Olgun/0000-0001-8500-2088
dc.authorwosidKarataş, Mert Olgun/ABG-7848-2020
dc.contributor.authorKaratas, Mert Olgun
dc.date.accessioned2024-08-04T20:46:44Z
dc.date.available2024-08-04T20:46:44Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn the present study, synthesis and catalytic properties of palladium PEPPSI type complexes of cycloheptyl substituted N-heterocyclic carbene ligand were reported. Different N-coordinate ligands including pyridine, imidazole and thiazole derivatives were used to stabilize the complexes. Structures of complexes were established by H-1 NMR, C-13 NMR, IR spectroscopic methods and elemental analyses. All complexes were applied to Suzuki-Miyaura cross coupling reaction in aqueous media. After the optimization of reaction conditions, all complexes were tested on the cross coupling of five different aryl chloride derivatives and phenylboronic acid. Pyridine containing complex, 3a performed stronger catalytic performance than others. (C) 2019 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.jorganchem.2019.120906
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85071328257en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2019.120906
dc.identifier.urihttps://hdl.handle.net/11616/98927
dc.identifier.volume899en_US
dc.identifier.wosWOS:000485104600002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCycloheptylen_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectPalladiumen_US
dc.subjectSuzuki-Miyaura reactionen_US
dc.titleCycloheptyl substituted N-heterocyclic carbene PEPPSI-type palladium complexes with different N-coordinated ligands: Involvement in Suzuki-Miyaura reactionen_US
dc.typeArticleen_US

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