Comparison of the catalytic performances of bridged bi-metallic and non-bridged mono-metallic PEPPSI type palladium N-heterocyclic carbene complexes

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dc.authoridKarataş, Mert Olgun/0000-0001-8500-2088
dc.authorwosidKarataş, Mert Olgun/ABG-7848-2020
dc.contributor.authorKaratas, Mert Olgun
dc.contributor.authorAlici, Bulent
dc.date.accessioned2024-08-04T20:47:13Z
dc.date.available2024-08-04T20:47:13Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractPalladium-N-heterocyclic carbene complexes are widely investigated catalysts in cross-coupling reactions. However, studies about the catalytic activities of bridged bi-metallic complexes are quite rare. Therefore, in this study, anthracene-substituted one mono-metallic and one bridged bi-metallic PEPPSI-type Pd-NHC complexes were synthesized in order to compare their catalytic activities in Suzuki-Miyaura and Mizoroki-Heck reactions. Both complexes were fully characterized by H-1 and C-13 NMR, LC-MS, IR spectra and elemental analyses. The results of catalytic reactions clearly revealed that mono-metallic complex performs better catalytic activity than bi-metallic analogue in the use of same amount of palladium.en_US
dc.identifier.doi10.1016/j.inoche.2020.107890
dc.identifier.issn1387-7003
dc.identifier.issn1879-0259
dc.identifier.scopus2-s2.0-85082744805en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.inoche.2020.107890
dc.identifier.urihttps://hdl.handle.net/11616/99240
dc.identifier.volume116en_US
dc.identifier.wosWOS:000530085000006en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofInorganic Chemistry Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjectBi-metallic complexesen_US
dc.subjectPalladiumen_US
dc.subjectCatalysisen_US
dc.titleComparison of the catalytic performances of bridged bi-metallic and non-bridged mono-metallic PEPPSI type palladium N-heterocyclic carbene complexesen_US
dc.typeArticleen_US

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