Zirconium tetra-n-butylate modified with different organic acids: Hydrolysis and polymerization of the products

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dc.authorscopusid6602628805
dc.authorscopusid35609517600
dc.authorscopusid6603040930
dc.contributor.authorSayilkan H.
dc.contributor.authorŞener S.
dc.contributor.authorArpaç E.
dc.date.accessioned2024-08-04T20:00:45Z
dc.date.available2024-08-04T20:00:45Z
dc.date.issued1994
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this work, (a) complexation reaction of zirconium tetra-n-butylate, Zr(OBun)4, with MAc and different organic acids, (b) the hydrolysis reaction of modified Zr species, and (c) the polymerization reaction of complex products are studied. Zr(OBun)4 was reacted with different mole ratios of methacrylic acid (MAc) at room temperature and the maximum combination ratio was found to be 1:2 [Zr(OBun)4:MAc] by FT-IR. The modification of zirconium tetra-n-butylate with the acid mixtures [methacrylic acid-acetic acid (MeCOOH), methacrylic acid-propionic acid (EtCOOH), methacrylic acid-butyric acid (PrCOOH)] was made for a combination ratio of 1:1:1 [MAc:RCOOH:Zr(OBun)4; R: Me, Et, Pr] and the products were characterized by1H-NMR, FT-IR, and UV spectroscopies. Following their synthesis, hydrolysis of the complexes with various amounts of water and polymerization with benzoyl peroxide were realized. The hydrolysis and polymerization products of the complexes were studied by Karl-Fischer coulometric titration and thermal analysis, respectively. Methyl ethyl ketone(MEK) and chloroform were chosen as solvents. © 1994 Plenum Publishing Corporation.en_US
dc.identifier.doi10.1007/BF00683722
dc.identifier.endpage314en_US
dc.identifier.issn1053-0495
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-0013695845en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage301en_US
dc.identifier.urihttps://doi.org/10.1007/BF00683722
dc.identifier.urihttps://hdl.handle.net/11616/90957
dc.identifier.volume4en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherKluwer Academic Publishers-Plenum Publishersen_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjecthydrolysis of metal alkoxidesen_US
dc.subjectinorganic-organic polymersen_US
dc.subjectSol-gel processingen_US
dc.subjectsynthesis of metal alkoxidesen_US
dc.titleZirconium tetra-n-butylate modified with different organic acids: Hydrolysis and polymerization of the productsen_US
dc.typeArticleen_US

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