Synthesis of sterically hindered N-benzyladamantyl substituted benzimidazol-2-ylidene palladium complexes and investigation of their catalytic activity in aqueous medium

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridPASAHAN, Aziz/0000-0002-0657-3884
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidPAŞAHAN, Aziz/ABI-3519-2020
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorDehimat, Zineb Imene
dc.contributor.authorPasahan, Aziz
dc.contributor.authorTebbani, Dahmane
dc.contributor.authorYasar, Sedat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:43:58Z
dc.date.available2024-08-04T20:43:58Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNHC-Pd-PEPPSI complexes with bulky benzyladamantyl substituted N-heterocyclic carbenes (NHC) were synthesized and characterized by NMR, HRMS, and micro analysis. These complexes were then used for Suzuki-Miyaura coupling reactions between aryl bromides and phenylboronic acid. With low catalyst, loading, all synthesized complexes rapidly catalyzed the Suzuki-Miyaura cross-coupling reaction in iPrOH/water (1:3 v/v) at room temperature in air. All palladium compounds were stable and had high catalytic activity for the Suzuki-Miyaura coupling reaction. (C) 2017 Elsevier Ltd. All rights reserved.en_US
dc.description.sponsorshipInonu University [BAP:2016/195]; University of Constantineen_US
dc.description.sponsorshipThis study was financially supported by the Inonu University research found (BAP:2016/195) and University of Constantine for grand Zineb Imene Dehimat.en_US
dc.identifier.doi10.1016/j.tet.2017.08.037
dc.identifier.endpage5945en_US
dc.identifier.issn0040-4020
dc.identifier.issue40en_US
dc.identifier.scopus2-s2.0-85028726416en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage5940en_US
dc.identifier.urihttps://doi.org/10.1016/j.tet.2017.08.037
dc.identifier.urihttps://hdl.handle.net/11616/97955
dc.identifier.volume73en_US
dc.identifier.wosWOS:000412036700016en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherPergamon-Elsevier Science Ltden_US
dc.relation.ispartofTetrahedronen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbene complexen_US
dc.subjectPalladiumen_US
dc.subjectSuzuki couplingen_US
dc.subjectGreen chemistryen_US
dc.titleSynthesis of sterically hindered N-benzyladamantyl substituted benzimidazol-2-ylidene palladium complexes and investigation of their catalytic activity in aqueous mediumen_US
dc.typeArticleen_US

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