1,3-Bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium trichlorido(?6-p-cymene)ruthenate(II)

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dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridArslan, Hakan/0000-0003-0046-9442
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidArslan, Hakan/B-1081-2008
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorArslan, Hakan
dc.contributor.authorVanDerveer, Don
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorGok, Yetkin
dc.contributor.authorCetinkaya, Bekir
dc.date.accessioned2024-08-04T20:31:06Z
dc.date.available2024-08-04T20:31:06Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe asymmetric unit of the title compound, (C14H17N2S2)-[Ru(C10H14)Cl-3], contains a 1,3-bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium cation and a trichlorido(eta(6)-p-cymene) ruthenate(II) anion. The Ru atom exhibits a distorted octahedral coordination with the benzene ring of the p-cymene ligand formally occupying three sites and three chloride atoms occupying the other three sites. The N-C bond lengths of the N-C-N unit of the pyrimidinium cation are shorter than the average single C-N bond length of 1.48 angstrom, thus showing double-bond character, indicating a partial electron delocalization within the N-C-N fragment. The pyrimidine ring has an envelope conformation. Four intermolecular C-H center dot center dot center dot Cl hydrogen bonds generate a three-dimensional hydrogen-bonded framework.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS [TBAG-U/181 (106 T716)]; Inonu University [2008-Gudumlu3]en_US
dc.description.sponsorshipWe thank the Technological and Scientific Research Council of Turkey TUBITAK-CNRS [TBAG-U/181 (106 T716)] and Inonu University Research Fund (B. A. P.: 2008-Gudumlu3) for financial support.en_US
dc.identifier.doi10.1107/S1600536808042773
dc.identifier.endpageU1137en_US
dc.identifier.issn1600-5368
dc.identifier.pmid21581477en_US
dc.identifier.scopus2-s2.0-58149459296en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpageM111en_US
dc.identifier.urihttps://doi.org/10.1107/S1600536808042773
dc.identifier.urihttps://hdl.handle.net/11616/94728
dc.identifier.volume65en_US
dc.identifier.wosWOS:000262234500089en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherWiley-Blackwellen_US
dc.relation.ispartofActa Crystallographica Section E-Structure Reports Onlineen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectN-Heterocyclic Carbenesen_US
dc.subjectCrystal-Structureen_US
dc.subjectCoupling Reactionsen_US
dc.subjectComplexesen_US
dc.subjectArylationen_US
dc.subjectCatalysisen_US
dc.subjectChloridesen_US
dc.subjectSaltsen_US
dc.title1,3-Bis(thiophen-2-ylmethyl)-3,4,5,6-tetrahydropyrimidinium trichlorido(?6-p-cymene)ruthenate(II)en_US
dc.typeArticleen_US

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