Syntheses and properties of metal containing polyimides based on the gold carbene complex

dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.contributor.authorSeckin, T
dc.contributor.authorKoytepe, S
dc.contributor.authorOzdemir, I
dc.contributor.authorÇetinkaya, B
dc.date.accessioned2024-08-04T20:13:17Z
dc.date.available2024-08-04T20:13:17Z
dc.date.issued2003
dc.departmentİnönü Üniversitesien_US
dc.description.abstractA novel gold carbene complex, bis(1,3-di-p-dimethylaminobenzylimidazolidinylidene) gold(I), was synthesized and polymerized to polyimides in a one-step method with various aromatic dianhyrides. The gold-coordinated polyimides are characterized by IR and NMR (H-1, C-13) spectroscopy. The materials have inherent viscosities that range from 1.88 to 2.39 dl/g and show excellent solubility in N-methylpyrrolidone and N,N-dimethylacetamide. The glass transition temperatures of the coordinated polyimides range from 203-265degreesC and a 5% weight loss in air is observed from 535-578degreesC. The polymers form dark yellow, tough films that are transparent above 365 nm. The effect of different flexible units on the properties of the polyimides is discussed.en_US
dc.identifier.doi10.1023/A:1022905015133
dc.identifier.endpage20en_US
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.issue1en_US
dc.identifier.scopus2-s2.0-0037366425en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage9en_US
dc.identifier.urihttps://doi.org/10.1023/A:1022905015133
dc.identifier.urihttps://hdl.handle.net/11616/93500
dc.identifier.volume13en_US
dc.identifier.wosWOS:000181795300002en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectpolyimideen_US
dc.subjectgold(I) coordinated polyimidesen_US
dc.subjectorganometallic polymeren_US
dc.subjectcarbene complexesen_US
dc.titleSyntheses and properties of metal containing polyimides based on the gold carbene complexen_US
dc.typeArticleen_US

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