Syntheses and properties of metal containing polyimides based on the gold carbene complex
dc.authorid | Özdemir, İsmail/0000-0001-6325-0216 | |
dc.authorid | Cetinkaya, Bekir/0000-0002-4551-8650 | |
dc.authorid | Koytepe, Suleyman/0000-0002-4788-278X | |
dc.authorwosid | Özdemir, İsmail/ABI-5192-2020 | |
dc.authorwosid | Köytepe, Süleyman/AAA-4168-2021 | |
dc.contributor.author | Seckin, T | |
dc.contributor.author | Koytepe, S | |
dc.contributor.author | Ozdemir, I | |
dc.contributor.author | Çetinkaya, B | |
dc.date.accessioned | 2024-08-04T20:13:17Z | |
dc.date.available | 2024-08-04T20:13:17Z | |
dc.date.issued | 2003 | |
dc.department | İnönü Üniversitesi | en_US |
dc.description.abstract | A novel gold carbene complex, bis(1,3-di-p-dimethylaminobenzylimidazolidinylidene) gold(I), was synthesized and polymerized to polyimides in a one-step method with various aromatic dianhyrides. The gold-coordinated polyimides are characterized by IR and NMR (H-1, C-13) spectroscopy. The materials have inherent viscosities that range from 1.88 to 2.39 dl/g and show excellent solubility in N-methylpyrrolidone and N,N-dimethylacetamide. The glass transition temperatures of the coordinated polyimides range from 203-265degreesC and a 5% weight loss in air is observed from 535-578degreesC. The polymers form dark yellow, tough films that are transparent above 365 nm. The effect of different flexible units on the properties of the polyimides is discussed. | en_US |
dc.identifier.doi | 10.1023/A:1022905015133 | |
dc.identifier.endpage | 20 | en_US |
dc.identifier.issn | 1574-1443 | |
dc.identifier.issn | 1574-1451 | |
dc.identifier.issue | 1 | en_US |
dc.identifier.scopus | 2-s2.0-0037366425 | en_US |
dc.identifier.scopusquality | Q2 | en_US |
dc.identifier.startpage | 9 | en_US |
dc.identifier.uri | https://doi.org/10.1023/A:1022905015133 | |
dc.identifier.uri | https://hdl.handle.net/11616/93500 | |
dc.identifier.volume | 13 | en_US |
dc.identifier.wos | WOS:000181795300002 | en_US |
dc.identifier.wosquality | N/A | en_US |
dc.indekslendigikaynak | Web of Science | en_US |
dc.indekslendigikaynak | Scopus | en_US |
dc.language.iso | en | en_US |
dc.publisher | Springer | en_US |
dc.relation.ispartof | Journal of Inorganic and Organometallic Polymers and Materials | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.rights | info:eu-repo/semantics/closedAccess | en_US |
dc.subject | polyimide | en_US |
dc.subject | gold(I) coordinated polyimides | en_US |
dc.subject | organometallic polymer | en_US |
dc.subject | carbene complexes | en_US |
dc.title | Syntheses and properties of metal containing polyimides based on the gold carbene complex | en_US |
dc.type | Article | en_US |