Crystal structure of 1,3-bis(4-methylbenzyl)-1H-1,3-benzimidazol-3-ium bromide monohydrate

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dc.authoridCelik, Omer/0000-0002-3314-6132
dc.authoridAkkurt, Mehmet/0000-0003-2421-0929
dc.authoridAkkoc, Senem/0000-0002-1260-9425
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.authorwosidİLHAN, İLHAN ÖZER/AAN-1469-2021
dc.authorwosidAkkoç, Senem/AAN-1478-2021
dc.contributor.authorCelikesir, Sevim Turktekin
dc.contributor.authorCelik, Omer
dc.contributor.authorAkkoc, Senem
dc.contributor.authorIlhan, Ilhanb Ozer
dc.contributor.authorGok, Yetkin
dc.contributor.authorAkkurt, Mehmet
dc.date.accessioned2024-08-04T20:40:10Z
dc.date.available2024-08-04T20:40:10Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn the title hydrated symetrically substituted 1,3-bis(4-methyl-benzyl) benzimidazolium salt, C23H23N2+center dot Br-center dot H2O, the dihedral angles between the benzimidazole ring system (r.m.s. deviation = 0.003 angstrom) and the pendant benzene rings are 73.18 (16) and 77.52 (16)degrees. Both benzene rings lie to the same side of the benzimidazole ring system, giving the cation an overall U-shape. In the crystal, the cation is linked to the water molecule by a short C-H center dot center dot center dot O hydrogen bond and the water molecule forms O-H center dot center dot center dot Br hydrogen bonds. Together, these interactions lead to [010] chains. The packing is consolidated by C-H center dot center dot center dot Br hydrogen bonds and aromatic pi-pi stacking interactions [centroid-centroid distances = 3.5401 (17) and 3.8815 (18) angstrom], generating a three-dimensional network.en_US
dc.identifier.doi10.1107/S2056989014025857
dc.identifier.endpage+en_US
dc.identifier.issn2056-9890
dc.identifier.pmid25705478en_US
dc.identifier.scopus2-s2.0-84928142743en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpageO10en_US
dc.identifier.urihttps://doi.org/10.1107/S2056989014025857
dc.identifier.urihttps://hdl.handle.net/11616/96758
dc.identifier.volume71en_US
dc.identifier.wosWOS:000369968500016en_US
dc.identifier.wosqualityN/Aen_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherInt Union Crystallographyen_US
dc.relation.ispartofActa Crystallographica Section E-Crystallographic Communicationsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectcrystal structureen_US
dc.subject1,3-bis(4-methylbenzyl)-1H-3,1-benzimidazol-3-ium bromide monohydrateen_US
dc.subjectbenzimidazolium saltsen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjecthydrogen bondsen_US
dc.subjectaromatic pi-pi stacking interactionsen_US
dc.titleCrystal structure of 1,3-bis(4-methylbenzyl)-1H-1,3-benzimidazol-3-ium bromide monohydrateen_US
dc.typeArticleen_US

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