Metallo-supramolecular materials based on terpyridine-functionalized polyhedral silsesquioxane

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dc.authoridGultek, Ahmet/0000-0002-4980-1568
dc.authoridSEÇKİN, Turgay/0000-0001-8483-7366
dc.authoridDemirel, Maruf Hursit/0000-0002-1274-407X
dc.authoridKoytepe, Suleyman/0000-0002-4788-278X
dc.authorwosidKöytepe, Süleyman/AAA-4168-2021
dc.authorwosidGultek, Ahmet/AAG-5735-2019
dc.authorwosidSEÇKİN, Turgay/ABG-7537-2020
dc.authorwosidDemirel, Maruf Hursit/W-7633-2018
dc.contributor.authorKoytepe, Sueleyman
dc.contributor.authorDemirel, Maruf Hursit
dc.contributor.authorGultek, Ahmet
dc.contributor.authorSeckin, Turgay
dc.date.accessioned2024-08-04T20:38:04Z
dc.date.available2024-08-04T20:38:04Z
dc.date.issued2014
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, novel metallo-supramolecular materials based on terpyridine-functionalized polyhedral silsesquioxane were synthesized from 4 '-chloro-2,2 ':6 ',2 ''-terpyridine and amino-group-functionalized polyhedral oligomeric silsesquioxane. The obtained terpyridine-functionalized polyhedral silsesquioxanes were converted to metallo-supramolecular hybrid materials by coordination polycondensation reaction with Co(II) or Cu(II) ions. The supramolecular polymers created were characterized by means of structure, morphology and stimuli-responsive performance employing scanning electron microscopy, amperometric techniques and UV-visible and Fourier transform IR spectroscopy. UV-visible and cyclic voltammetry studies showed that both the optical and electrochemical properties of metallo-supramolecular materials are affected by the substituent at the pyridine periphery. The supramolecular polymers obtained exhibited electrochromism during the oxidation processes of cyclic voltammogram studies. As a result, these terpyridine-functionalized polyhedral silsesquioxanes are good candidates for electronic, opto-electronic and photovoltaic applications as smart stimuli-responsive materials. (c) 2013 Society of Chemical Industryen_US
dc.description.sponsorshipTubitak - the Scientific and Technological Research Council of Turkey [MAG110M751]en_US
dc.description.sponsorshipAuthors would like to thank Tubitak - the Scientific and Technological Research Council of Turkey for financial support with project number MAG110M751.en_US
dc.identifier.doi10.1002/pi.4596
dc.identifier.endpage787en_US
dc.identifier.issn0959-8103
dc.identifier.issn1097-0126
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-84896709498en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage778en_US
dc.identifier.urihttps://doi.org/10.1002/pi.4596
dc.identifier.urihttps://hdl.handle.net/11616/96369
dc.identifier.volume63en_US
dc.identifier.wosWOS:000332393600026en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherWileyen_US
dc.relation.ispartofPolymer Internationalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectterpyridine ligandsen_US
dc.subjectPOSSen_US
dc.subjectsupramolecular polymersen_US
dc.subjectstimuli-responsive polymersen_US
dc.subjectcoordination chemistryen_US
dc.titleMetallo-supramolecular materials based on terpyridine-functionalized polyhedral silsesquioxaneen_US
dc.typeArticleen_US

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