High probability of large orbital angular momentum contribution to the magnetic moment of cobalt(II) ion in newly reported macrocyclic complex containing amide, imine and secondary amine functions

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dc.authorscopusid14047994100
dc.authorscopusid8964614400
dc.contributor.authorBayri A.
dc.contributor.authorAytekin O.
dc.date.accessioned2024-08-04T19:59:17Z
dc.date.available2024-08-04T19:59:17Z
dc.date.issued2008
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe magnetic moments of Co+2 complexes in newly reported macrocyclic complexes containing amide, imine, and secondary amine functions are investigated by a semi-theoretical approach for various geometrical situations. It is found that in order to obtain the observed room temperature magnetic moments, some of the parameters, related to the geometry of the complexes, should be varied in the magnetic Hamiltonian. The calculations and experiments obtained from the literature suggest that the environments of complexes are low field distorted octahedral. It is also suggested that while the probability of orbital contribution to the magnetic moment is high, the probability of ferromagnetic interactions between two cobalt(II) ions in a dimeric unit is quite low.en_US
dc.identifier.doi10.1515/REVIC.2008.28.3.203
dc.identifier.endpage216en_US
dc.identifier.issn0193-4929
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-56849129579en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage203en_US
dc.identifier.urihttps://doi.org/10.1515/REVIC.2008.28.3.203
dc.identifier.urihttps://hdl.handle.net/11616/90530
dc.identifier.volume28en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherFreund Publishing House Ltden_US
dc.relation.ispartofReviews in Inorganic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCobalt(II) complexen_US
dc.subjectCovalancy factoren_US
dc.subjectDistortionen_US
dc.subjectFerromagnetic exchangeen_US
dc.subjectMagnetic susceptibilityen_US
dc.subjectMagnetizationen_US
dc.subjectOrbital contributionen_US
dc.subjectSpin-orbit couplingen_US
dc.titleHigh probability of large orbital angular momentum contribution to the magnetic moment of cobalt(II) ion in newly reported macrocyclic complex containing amide, imine and secondary amine functionsen_US
dc.typeArticleen_US

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