N-Propylphthalimide-Substituted Silver(I) N-Heterocyclic Carbene Complexes and Ruthenium(II) N-Heterocyclic Carbene Complexes: Synthesis and Transfer Hydrogenation of Ketones

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dc.authoridAktaş, Aydın/0000-0001-8496-6782;
dc.authorwosidAktaş, Aydın/J-6194-2019
dc.authorwosidGök, Yetkin/AAA-5669-2021
dc.contributor.authorAktas, Aydin
dc.contributor.authorGok, Yetkin
dc.date.accessioned2024-08-04T20:40:20Z
dc.date.available2024-08-04T20:40:20Z
dc.date.issued2015
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThis study deals with the synthesis of N-propylphthalimide substituted Ag(I)-N-heterocyclic carbene (NHC) complexes and N-propylphthalimide substituted Ru(II)-NHC complexes in the transfer hydrogenation of ketones. The Ag(I)-NHC complexes were synthesized from the imidazolium salts and Ag2O in dichloromethane at room temperature. The Ru(II)-NHC complexes have been prepared from Ag(I)-NHC complexes using transmetallation method. The six N-propylphthalimide substituted Ag(I)-NHC complexes and six N-propylphthalimide substituted Ru(II)-NHC complexes have been characterized by spectroscopic techniques and elemental analyses. N-propylphthalimide substituted Ru(II)-NHC complexes have been analyzed as catalysts for the transfer hydrogenation of ketones and exhibit activity in this reaction. This study deals with the synthesis of N-propylphthalimide substituted Ag(I)-N-heterocyclic carbene (NHC) complexes and N-propylphthalimide substituted Ru(II)-NHC complexes in the transfer hydrogenation of ketones. The Ag(I)-NHC complexes were synthesized from the imidazolium salts and Ag2O in dichloromethane at room temperature. The Ru(II)-NHC complexes have been prepared from Ag(I)-NHC complexes using transmetallation method. The six N-propylphthalimide substituted Ag(I)-NHC complexes and six N-propylphthalimide substituted Ru(II)-NHC complexeshavebeencharacterizedbyspectroscopictechniquesandelementalanalyses. N-propylphthalimide substituted Ru(II)-NHC complexes have been analyzed as catalysts for the transfer hydrogenation of ketones and exhibit activity in this reaction.en_US
dc.identifier.doi10.1007/s10562-014-1453-8
dc.identifier.endpage639en_US
dc.identifier.issn1011-372X
dc.identifier.issn1572-879X
dc.identifier.issue2en_US
dc.identifier.scopus2-s2.0-84936093238en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage631en_US
dc.identifier.urihttps://doi.org/10.1007/s10562-014-1453-8
dc.identifier.urihttps://hdl.handle.net/11616/96860
dc.identifier.volume145en_US
dc.identifier.wosWOS:000349553000018en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCatalysis Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectN-heterocyclic carbenesen_US
dc.subjectSilver and ruthenium complexesen_US
dc.subjectCatalysisen_US
dc.subjectTransfer hydrogenationen_US
dc.titleN-Propylphthalimide-Substituted Silver(I) N-Heterocyclic Carbene Complexes and Ruthenium(II) N-Heterocyclic Carbene Complexes: Synthesis and Transfer Hydrogenation of Ketonesen_US
dc.typeArticleen_US

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