Fabrication and electrochemical performance of Ho-substituted C/LiFePO4: Improved battery performance
Küçük Resim Yok
Tarih
2021
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Springer
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Ho-substituted C/LiFePO4 samples were successfully fabricated, and their structural properties were examined by X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR) measurements. The magnetic structure of LiFePO4 correspondence to the high spin configuration of Fe2+ ions and Ho3+ causes the increase of the mu(eff) values and suppressed the antiferromagnetic transition. The XRD analysis showed an amorphous structure due to carbon, and peaks were matched by olivine-type LiFePO4. Furthermore, the lattice volume was increased with the addition of Ho. The Ho-substituted cells show similar cycling voltammetry (CV) graphs with the CV of the undoped LiFePO4 cells. According to charge/discharge cycling measurements for constant current at room temperature, the highest capacity was obtained for LiFe0.99Ho0.01PO4. The Ho-substituted LiFePO4 has a higher C-rate when compared with the undoped LiFePO4 and so it is found that a low concentration of Ho in LiFePO4 has better battery performance and may be used in commercial batteries.
Açıklama
Anahtar Kelimeler
Olivine-Type Lifepo4, Cathode Material, Doped Lifepo4/C, Magnetic-Properties, Ion Battery, Lithium, Carbon, Mn, Co, Mechanism
Kaynak
Journal of Materials Science-Materials in Electronics
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
32
Sayı
16
