Unveiling the outstanding full-cell performance of P2-type Na0.67(Mn0.44Ni0.06Fe0.43Ti0.07)O2 cathode active material for Na-ion batteries
Küçük Resim Yok
Tarih
2024
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this study, we unravel the effect of Ni doping on the half-cell and full-cell performances of the Na0.67Mn0.5-xNixFe0.43Ti0.07O2 cathode materials where x varies between 0.02 and 0.1. The cyclic voltammetry (CV) analysis of the half-cells is performed at 10 degrees C, room temperature (RT), and 50 degrees C to elucidate the redox reaction mechanisms at different temperatures. Among the studied cathodes, the highest specific capacity is obtained fox = 0.06 which delivered a specific capacity of 186 mAh g-1 at C/3-rate. The full cell of Na0.67Mn0.44Ni0.06-Fe0.43Ti0.07O2/hard carbon couple is assembled in coin cell format and the specific capacity of the cell at C/2, 1C, and 2C rates are found as 153 mAh g- 1, 125 mAh g-1 and 120 mAh g-1, respectively. At the C/2-rate, the excellent capacity retention of the full cell is around 70% after 500 cycles delivering a specific capacity of 103 mAh g- 1. Along with the conventional physicochemical characterization methods such as X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), Raman and Fourier-transform Infrared Spectroscopies (FTIR), we also utilize X-ray photoelectron spectroscopy (XPS) to bridge the nexus between the performance and the structure properties of the studied materials. Furthermore, we also employ synchrotron-based X-ray Absorption (XAS) to understand the local geometry of the optimized cathode materials in operando.
Açıklama
Anahtar Kelimeler
Na-ion full cell, Operando XAS
Kaynak
Journal of Power Sources
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
591
