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  • Küçük Resim
    Öğe
    In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[$RuCl_2(p-cymene)]_2$ system for transfer hydrogenation reactions
    (2011) Özcan, Emine Özge; Mercan, Deniz; Gürbüz, Nevin; Çetinkaya, Engin; Çetinkaya, Bekir; Özdemir, İsmail
    Abstract: Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[
  • Küçük Resim Yok
    Öğe
    In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl2(p-cymene)]2 system for transfer hydrogenation reactions
    (Tubitak Scientific & Technological Research Council Turkey, 2011) Ozcan, Emine Ozge; Mercan, Deniz; Gurbuz, Nevin; Cetinkaya, Engin; Cetinkaya, Bekir; Ozdemir, Ismail
    Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3-dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p-cymene)](2) and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.
  • Küçük Resim
    Öğe
    In situ catalytic activities of 1,3-dialkyltetrahydropyrimidinium salts/[RuCl_2(p-cymene)]_2 system for transfer hydrogenation reactions
    (Turkish Journal of Chemistry, 2011) Özcan, Emine Özge; Mercan, Deniz; Gürbüz, Nevin; Çetinkaya, Engin; Çetinkaya, Bekir; Özdemir, İsmail
    Abstract: Hydrogen-transfer reduction processes are attracting increasing interest from synthetic chemists in view of their operational simplicity. In the present study novel ruthenium carbene complexes were generated in situ and tested for their transfer hydrogenation reactions. The in situ prepared 3 component 1,3- dialkyltetrahydropyrimidinium salts (LHX)/[RuCl2(p?cymene)]2 and KOH catalyzed quantitatively the transfer hydrogenation of ketones under mild reaction conditions in 2-propanol.