Synthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitriles
Küçük Resim Yok
Tarih
2013
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Benzimidazolium salts and their new rhodium complexes ([RH(COD)(NHC)Cl]) were synthesized and characterized by elemental analysis, H-1 NMR, C-13 NMR, and IR spectroscopy. The addition of arylboron to benzonitriles in the presence of a catalytic amount of rhodium NHC complexes was examined. Corresponding carbonyl compounds were obtained in good yields. This method allows for the preparation of a wide variety of carbonyl compounds in moderate to excellent yields and displays a high level of activity for the addition of arylboron to nitriles. (C) 2013 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Rh-NHC, Benzimidazolin-2-ylidene, Sodium tetraphenylborate, Ketone, Arylation of nitrile
Kaynak
Journal of Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
732
