Synthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitriles

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridDüşünceli, Serpil Demir/0000-0001-8765-4039
dc.authorwosidDemir, Serpil/AAI-1740-2019
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidDüşünceli, Serpil Demir/AAA-7160-2021
dc.contributor.authorDemir, Serpil
dc.contributor.authorYigit, Murat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:37:27Z
dc.date.available2024-08-04T20:37:27Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractBenzimidazolium salts and their new rhodium complexes ([RH(COD)(NHC)Cl]) were synthesized and characterized by elemental analysis, H-1 NMR, C-13 NMR, and IR spectroscopy. The addition of arylboron to benzonitriles in the presence of a catalytic amount of rhodium NHC complexes was examined. Corresponding carbonyl compounds were obtained in good yields. This method allows for the preparation of a wide variety of carbonyl compounds in moderate to excellent yields and displays a high level of activity for the addition of arylboron to nitriles. (C) 2013 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipInonu University Research Funden_US
dc.description.sponsorshipThis work was financially supported by Inonu University Research Fund.en_US
dc.identifier.doi10.1016/j.jorganchem.2013.01.025
dc.identifier.endpage26en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-84874930434en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage21en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2013.01.025
dc.identifier.urihttps://hdl.handle.net/11616/95981
dc.identifier.volume732en_US
dc.identifier.wosWOS:000318319400004en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRh-NHCen_US
dc.subjectBenzimidazolin-2-ylideneen_US
dc.subjectSodium tetraphenylborateen_US
dc.subjectKetoneen_US
dc.subjectArylation of nitrileen_US
dc.titleSynthesis of rhodium complexes derived from benzimidazolin-2-ylidene ligands and first used for the addition of arylboron to benzonitrilesen_US
dc.typeArticleen_US

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