Polyimides from a novel monomer 3,6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium(II) for a catalytic application
Küçük Resim Yok
Tarih
2004
Yazarlar
Dergi Başlığı
Dergi ISSN
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Yayıncı
Springer New York LLC
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Tricyclic heteroaraomatic dye-based monomer containing NMe2 units, 6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium (II), was used to prepare novel polyimides via a one-stage solution polycondensation due to their stability under a variety of oxidative and reductive conditions. The Ru(II) complex monomer was synthesized starting from [RuCl2 (p-cymene)]2 and 3,6-bis(dimethylamino)acridine. A series of stable polyimides was synthesized from the Ru(II) complex of 3,6-e/5(dimethylamino)acridine and various aromatic dianhyrides. The polymers had inherent viscosities ranging from 1.72 to 2.11 dL/g and were soluble in polar solvents. The glass transition temperatures were 192-278 °C, and the 10% weight loss temperatures were above 503-635 °C. Ruthenium-substituted polyimides were tested for catalytic activity in the furan formation reaction of (Z)-3-methylpent-2-en-4-yn-l-ol. The polymeric catalyst was added to (Z)-3-methylpent-2-en-4-yn-l-ol without a solvent and the pure furan was isolated by distillation under reduced pressure. The conversion of the starting, enynol, was determined by gas chromatography (GC). © 2004 Springer Science+Business Media, Inc.
Açıklama
Anahtar Kelimeler
Catalyst, Furan formation reaction, Polyimide, Ruthenium(ii) complex, Thermally stable polymers
Kaynak
Journal of Inorganic and Organometallic Polymers and Materials
WoS Q Değeri
Scopus Q Değeri
Q2
Cilt
14
Sayı
3
