Polyimides from a novel monomer 3,6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium(II) for a catalytic application

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dc.authorscopusid57195458120
dc.authorscopusid6603283338
dc.authorscopusid7005334934
dc.authorscopusid37042192100
dc.authorscopusid7006471258
dc.contributor.authorSeckin T.
dc.contributor.authorKoytepe S.
dc.contributor.authorOzdemir I.
dc.contributor.authorGiirbiiz N.
dc.contributor.authorÇetinkaya B.
dc.date.accessioned2024-08-04T20:02:29Z
dc.date.available2024-08-04T20:02:29Z
dc.date.issued2004
dc.departmentİnönü Üniversitesien_US
dc.description.abstractTricyclic heteroaraomatic dye-based monomer containing NMe2 units, 6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium (II), was used to prepare novel polyimides via a one-stage solution polycondensation due to their stability under a variety of oxidative and reductive conditions. The Ru(II) complex monomer was synthesized starting from [RuCl2 (p-cymene)]2 and 3,6-bis(dimethylamino)acridine. A series of stable polyimides was synthesized from the Ru(II) complex of 3,6-e/5(dimethylamino)acridine and various aromatic dianhyrides. The polymers had inherent viscosities ranging from 1.72 to 2.11 dL/g and were soluble in polar solvents. The glass transition temperatures were 192-278 °C, and the 10% weight loss temperatures were above 503-635 °C. Ruthenium-substituted polyimides were tested for catalytic activity in the furan formation reaction of (Z)-3-methylpent-2-en-4-yn-l-ol. The polymeric catalyst was added to (Z)-3-methylpent-2-en-4-yn-l-ol without a solvent and the pure furan was isolated by distillation under reduced pressure. The conversion of the starting, enynol, was determined by gas chromatography (GC). © 2004 Springer Science+Business Media, Inc.en_US
dc.description.sponsorship101T029, IU BAP 2003/69en_US
dc.description.sponsorshipWe gratefully acknowledge the support of this research by the TUBI-TAK, Turkish Research Council TBAG 2017 (101T029), and IU BAP 2003/69 for partial support.en_US
dc.identifier.doi10.1023/b:joip.0000039366.65792.68
dc.identifier.endpage190en_US
dc.identifier.issn1574-1443
dc.identifier.issue3en_US
dc.identifier.scopus2-s2.0-4444284389en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage177en_US
dc.identifier.urihttps://doi.org/10.1023/b:joip.0000039366.65792.68
dc.identifier.urihttps://hdl.handle.net/11616/91735
dc.identifier.volume14en_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringer New York LLCen_US
dc.relation.ispartofJournal of Inorganic and Organometallic Polymers and Materialsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectCatalysten_US
dc.subjectFuran formation reactionen_US
dc.subjectPolyimideen_US
dc.subjectRuthenium(ii) complexen_US
dc.subjectThermally stable polymersen_US
dc.titlePolyimides from a novel monomer 3,6-bis(dimethylamino)acridine(p-cymene)dichlororuthenium(II) for a catalytic applicationen_US
dc.typeArticleen_US

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