Efficiency enhancement with chloride to iodide ion exchange of benzimidazolium salt as a redox mediator

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dc.authoridDAYAN, Serkan/0000-0003-4171-7297
dc.authoridKaratas, Mert Olgun/0000-0001-8500-2088
dc.authoridALICI, BULENT/0000-0001-5009-3223
dc.authorwosidDAYAN, Serkan/J-7189-2019
dc.contributor.authorDayan, Serkan
dc.contributor.authorKaratas, Mert Olgun
dc.contributor.authorAlici, Bulent
dc.contributor.authorKalaycioglu Ozpozan, Nilgun
dc.date.accessioned2024-08-04T20:10:05Z
dc.date.available2024-08-04T20:10:05Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe new benzimidazolium derivative (SM-1) salt with ion exchange from the (SM-0) was fabricated and characterized by proton-nuclear magnetic resonance (H-1-NMR), carbon-nuclear magnetic resonance (C-13-NMR), Fourier-transform infrared spectroscopy (FTIR), electrospray ionization (EIS-MS), thermal analysis (TG), cyclic voltammetry (CV), and ultraviolet-visible spectroscopy (UV-vis), for electrolytes (liquid or dried) in the DSSC charge transportation mechanism. Also, the influence of ion exchange from chloride to iodine in the synthesized electrolytes, compared to other electrolytes (conventional or commercial), was investigated about DSSC performance efficiency. When using as a liquid electrolyte (SM-1), the power conversion efficiency (eta) of the working DSSC device was recorded as 1.980% and it was observed that the performances of DSSCs increased up to 56% when comparing dried electrolyte for SM-1 without conventional redox material (I-/I3-). In the future, different molecular modifications of this type of benzimidazole derivatives or mixtures with conventional redox couples may further improve the performance of DSSC devices.en_US
dc.identifier.doi10.3906/kim-2006-25
dc.identifier.endpage+en_US
dc.identifier.issn1300-0527
dc.identifier.issue2en_US
dc.identifier.pmid34121846en_US
dc.identifier.scopus2-s2.0-85106208273en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage333en_US
dc.identifier.trdizinid525415en_US
dc.identifier.urihttps://doi.org/10.3906/kim-2006-25
dc.identifier.urihttps://search.trdizin.gov.tr/yayin/detay/525415
dc.identifier.urihttps://hdl.handle.net/11616/92594
dc.identifier.volume45en_US
dc.identifier.wosWOS:000644696500006en_US
dc.identifier.wosqualityQ4en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakTR-Dizinen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherTubitak Scientific & Technological Research Council Turkeyen_US
dc.relation.ispartofTurkish Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectBenzimidazoleen_US
dc.subjectDSSCen_US
dc.subjectphotovoltaicsen_US
dc.subjectdye-sensitized solar cellen_US
dc.titleEfficiency enhancement with chloride to iodide ion exchange of benzimidazolium salt as a redox mediatoren_US
dc.typeArticleen_US

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