Proving hydrogen addition mechanism from manure to coal surface obtained by GC-MS and 1H-NMR analysis

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dc.authoridKaraca, Huseyin/0000-0002-0543-8947
dc.authorwosidKaraca, Huseyin/ABG-8103-2020
dc.contributor.authorKoyunoglu, Cemil
dc.contributor.authorKaraca, Huseyin
dc.date.accessioned2024-08-04T20:46:01Z
dc.date.available2024-08-04T20:46:01Z
dc.date.issued2019
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, to explain the possibility of hydrogen transfer paths from manure to coal, Elbistan lignite (EL) combined with manure liquefaction of oil + gas products were analysed with Gas Chromatography-Mass Spectroscopy (GC-MS) and Nuclear Magnetic Resonance Spectroscopy (H-1-NMR) technique. In the same way, it is observed that oils which as they fragment to an alkane-alkene mixture, serve as a hydrogen sponge and put a serious hydrogen need on the parts of the free radicals and molecules that are currently hydrogen poor. Concerning Elbistan lignite and manure do not have any aromatic hydrogen. Moreover, when the aromatic compounds were hydrogenated, their aromatic hydrogen was transformed to naphthenic hydrogen. Hydrogen transfer was due to isomerization of heptane from 3-methylhexane obtained in test oil where only manure was present as hydrogen donor in the liquefaction environment despite hydrogenation of isomerization from naphthalene to azulene.en_US
dc.description.sponsorshipInonu University Scientific Research Projects Coordination Unit [I.U.B.A.P.B. 2008/03]en_US
dc.description.sponsorshipIt is a pleasure to acknowledge the support of this work (Project No: I.U.B.A.P.B. 2008/03) by Inonu University Scientific Research Projects Coordination Unit. Thanks, Associate Professor Doctor Mehmet Atilla Tasdelen (Yalova University, Department of Polymer Engineering) for obtaining 1H-NMR analysis and his valuable comments.en_US
dc.identifier.doi10.1038/s41598-019-45254-4
dc.identifier.issn2045-2322
dc.identifier.pmid31235778en_US
dc.identifier.scopus2-s2.0-85067870292en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.urihttps://doi.org/10.1038/s41598-019-45254-4
dc.identifier.urihttps://hdl.handle.net/11616/98842
dc.identifier.volume9en_US
dc.identifier.wosWOS:000472597400108en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherNature Portfolioen_US
dc.relation.ispartofScientific Reportsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectLiquefactionen_US
dc.subjectLigniteen_US
dc.subjectOilen_US
dc.subjectWateren_US
dc.subjectPolymerizationen_US
dc.subjectSpectroscopyen_US
dc.subjectExtractionen_US
dc.subjectPyrolysisen_US
dc.subjectCatalystsen_US
dc.subjectProductsen_US
dc.titleProving hydrogen addition mechanism from manure to coal surface obtained by GC-MS and 1H-NMR analysisen_US
dc.typeArticleen_US

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