Synthesis and catalytic activity of ionic palladium N-heterocyclic carbene complexes
Küçük Resim Yok
Tarih
2019
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Tubitak Scientific & Technological Research Council Turkey
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The synthesis of 3 benzimidazole-based ionic Pd(II)-NHC complexes (NHC: N-heterocyclic carbene) is presented. The structures of the complexes are as follows: [NHC-PdBr3](-) [NHC](+). The ionic palladium(II)-NHC complexes were synthesized in high yields and were fully characterized by nuclear magnetic resonance spectroscopy, X-ray diffraction, LC-MS/MS, and elemental analysis. These complexes have been identified as active catalysts in Suzuki-Miyaura reactions in a solution of 2-propanol and water at room temperature for different aryl bromides.
Açıklama
Anahtar Kelimeler
Ionic palladium complex, N-heterocyclic carbene, C-C bond formation, anionic palladium species, Suzuki-Miyaura cross-coupling reactions
Kaynak
Turkish Journal of Chemistry
WoS Q Değeri
Q4
Scopus Q Değeri
Q3
Cilt
43
Sayı
6
