The catalytic effects of in situ prepared N-heterocyclic carbenes from benzimidazole salts in Suzuki–Miyaura cross-coupling reaction and uses in catalytic preparation of 1,3,5-triphenyl-1,3,5-triazinane-2,4,6-trione from phenyl isocyanate
| dc.contributor.author | Küçükbay, Hasan | |
| dc.contributor.author | Yılmaz, Ülkü | |
| dc.date.accessioned | 2021-11-09T15:54:10Z | |
| dc.date.available | 2021-11-09T15:54:10Z | |
| dc.date.issued | 2018 | |
| dc.department | İnönü Üniversitesi | en_US |
| dc.description.abstract | Abstract: Many benzimidazole salts bearing a 3-phenylpropyl substituent (1a–1h) were synthesized and their structures were identified by 1 H NMR, 13 C NMR, and IR spectroscopic methods and elemental analysis. These N-heterocyclic carbene (NHC) precursors were used as a part of a catalytic system including Pd(OAc) 2 and the base in the Suzuki– Miyaura cross-coupling reaction under microwave irradiation. They were also used as catalysts in the cyclotrimerization of phenyl isocyanate to yield 1,3,5-triphenyl-1,3,5-triazinane-2,4,6-trione. It has been observed that benzimidazole salts made a positive contribution to both catalytic reactions as a NHC precursor. | en_US |
| dc.identifier.citation | YILMAZ Ü,KÜÇÜKBAY H (2018). The catalytic effects of in situ prepared N-heterocyclic carbenes from benzimidazole salts in Suzuki–Miyaura cross-coupling reaction and uses in catalytic preparation of 1,3,5-triphenyl-1,3,5-triazinane-2,4,6-trione from phenyl isocyanate . Turkish Journal of Chemistry, 42(6), 1706 - 1719. Doi: 10.3906/kim-1804-39 | en_US |
| dc.identifier.doi | 10.3906/kim-1804-39 | en_US |
| dc.identifier.endpage | 1719 | en_US |
| dc.identifier.issn | 1300-0527 | |
| dc.identifier.issn | 1303-6130 | |
| dc.identifier.issue | 6 | en_US |
| dc.identifier.scopus | 2-s2.0-85059040033 | en_US |
| dc.identifier.scopusquality | Q3 | en_US |
| dc.identifier.startpage | 1706 | en_US |
| dc.identifier.trdizinid | 381510 | en_US |
| dc.identifier.uri | https://doi.org/10.3906/kim-1804-39 | |
| dc.identifier.uri | https://hdl.handle.net/11616/43044 | |
| dc.identifier.uri | https://search.trdizin.gov.tr/yayin/detay/381510 | |
| dc.identifier.volume | 42 | en_US |
| dc.identifier.wos | WOS:000452163800019 | en_US |
| dc.identifier.wosquality | Q3 | en_US |
| dc.indekslendigikaynak | TR-Dizin | en_US |
| dc.indekslendigikaynak | Web of Science | en_US |
| dc.indekslendigikaynak | Scopus | en_US |
| dc.language.iso | en | en_US |
| dc.relation.ispartof | Turkish Journal of Chemistry | en_US |
| dc.relation.publicationcategory | Makale - Ulusal Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
| dc.rights | info:eu-repo/semantics/openAccess | en_US |
| dc.title | The catalytic effects of in situ prepared N-heterocyclic carbenes from benzimidazole salts in Suzuki–Miyaura cross-coupling reaction and uses in catalytic preparation of 1,3,5-triphenyl-1,3,5-triazinane-2,4,6-trione from phenyl isocyanate | en_US |
| dc.type | Article | en_US |
