Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex

Küçük Resim Yok

Tarih

2018

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Elsevier Science Sa

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

The synthesis of chelated ruthenium(II) complex type Ru(eta(6)-HMB) (NHC) Cl (NHC = N-heterocyclic carbene, HMB = hexamethylbenzene) is presented. The ruthenium(II)-NHC complex 6 was obtained in good yield and was fully characterised by NMR spectroscopy, X-ray diffraction and HRMS analysis. Electrochemical analysis by cyclic voltammetry (CV) revealed reversible redox behaviour at the ruthenium centre in 6. DFT studies and the catalytic activity of complex 6 on transfer hydrogenation reaction of aryl ketones are also presented. The potential hybrid capacitor applications of Ru-NHC complex is discussed and reported firstly in the literature. It was found that the highest performance was found at 20.1 F/g, which is a promising result for energy storage applications. (c) 2018 Elsevier B.V. All rights reserved.

Açıklama

Anahtar Kelimeler

Cyclic voltametry of ruthenium(II), Hybrid capasitor, N-heterocyclic carbene, Ruthenium, Chelate ligand, Transfer hydrogenation

Kaynak

Journal of Organometallic Chemistry

WoS Q Değeri

Q3

Scopus Q Değeri

Q3

Cilt

866

Sayı

Künye