Investigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complex

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dc.authoridAKKOÇ, Mitat/0000-0001-8641-8958
dc.authoridDemirel, Serkan/0000-0003-1158-4956
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridYaşar, Sedat/0000-0001-7285-2761
dc.authoridbruneau, christian/0000-0002-2220-1458
dc.authorwosidAKKOÇ, Mitat/AAJ-5780-2020
dc.authorwosidDemirel, Serkan/AAA-2133-2020
dc.authorwosidbayri, ali/AAA-5966-2021
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidBruneau, Christian/AAL-4582-2020
dc.authorwosidOz, Erdinc/GXW-0937-2022
dc.authorwosidYaşar, Sedat/ABG-8356-2020
dc.contributor.authorAkkoc, Mitat
dc.contributor.authorOz, Erdinc
dc.contributor.authorDemirel, Serkan
dc.contributor.authorDorcet, Vincent
dc.contributor.authorRoisnel, Thierry
dc.contributor.authorBayri, Ali
dc.contributor.authorBruneau, Christian
dc.date.accessioned2024-08-04T20:44:29Z
dc.date.available2024-08-04T20:44:29Z
dc.date.issued2018
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe synthesis of chelated ruthenium(II) complex type Ru(eta(6)-HMB) (NHC) Cl (NHC = N-heterocyclic carbene, HMB = hexamethylbenzene) is presented. The ruthenium(II)-NHC complex 6 was obtained in good yield and was fully characterised by NMR spectroscopy, X-ray diffraction and HRMS analysis. Electrochemical analysis by cyclic voltammetry (CV) revealed reversible redox behaviour at the ruthenium centre in 6. DFT studies and the catalytic activity of complex 6 on transfer hydrogenation reaction of aryl ketones are also presented. The potential hybrid capacitor applications of Ru-NHC complex is discussed and reported firstly in the literature. It was found that the highest performance was found at 20.1 F/g, which is a promising result for energy storage applications. (c) 2018 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipTUBITAK [114Z036]; TARLA project [2006K-120470]; Inonu University [2016/53, G2016/52]en_US
dc.description.sponsorshipThe author Prof. Sedat Yasar would like to thanks to TUBITAK (114Z036) for financial support to synthesis and characterisation of the complex 6, Dr. Serdar Altin also want to thanks to Inonu University under project numbers of 2016/53 and G2016/52 for the electrochemical and capacitive properties of complex 6, and Erdinc Oz want to thanks to TARLA project (project no: 2006K-120470) for the financial support.en_US
dc.identifier.doi10.1016/j.jorganchem.2018.04.035
dc.identifier.endpage222en_US
dc.identifier.issn0022-328X
dc.identifier.issn1872-8561
dc.identifier.scopus2-s2.0-85046754306en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage214en_US
dc.identifier.urihttps://doi.org/10.1016/j.jorganchem.2018.04.035
dc.identifier.urihttps://hdl.handle.net/11616/98278
dc.identifier.volume866en_US
dc.identifier.wosWOS:000432600900024en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.subjectCyclic voltametry of ruthenium(II)en_US
dc.subjectHybrid capasitoren_US
dc.subjectN-heterocyclic carbeneen_US
dc.subjectRutheniumen_US
dc.subjectChelate liganden_US
dc.subjectTransfer hydrogenationen_US
dc.titleInvestigation of potential hybrid capacitor property of chelated N-Heterocyclic carbene Ruthenium(II) complexen_US
dc.typeArticleen_US

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