Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes
Küçük Resim Yok
Tarih
2009
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Soc Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
The reaction of Pd(OAc)(2) with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl)benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr(2)bis(benzimidazolin-2- ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.
Açıklama
Anahtar Kelimeler
Direct Ortho Arylation, C-H Bonds, Transition-Metal-Complexes, Thin-Film Transistors, Transfer Hydrogenation, Alkene Metathesis, Mono-Carbene, Rhodium, Ligands, Alkenylation
Kaynak
Dalton Transactions
WoS Q Değeri
Q1
Scopus Q Değeri
Q1
Cilt
Sayı
35
