Synthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexes

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dc.authoridSahin, Onur/0000-0003-3765-3235
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidSahin, Onur/KGM-3910-2024
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorDogan, Oznur
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorCetinkaya, Bekir
dc.contributor.authorSahin, Onur
dc.contributor.authorBuyukgungor, Orhan
dc.date.accessioned2024-08-04T20:31:17Z
dc.date.available2024-08-04T20:31:17Z
dc.date.issued2009
dc.departmentİnönü Üniversitesien_US
dc.description.abstractThe reaction of Pd(OAc)(2) with 1-(benzhydryl)-3-(alkyl) benzimidazolium salts 1a-d yields trans-bis[1-(benzhydryl)-3-(alkyl)benzimidazolin-2-ylidene]dibromopalladium(II) complexes (2a-d) which were characterized by elemental analysis, NMR spectroscopy and the molecular structures of 2b, and 2d were determined by X-ray crystallography. The catalytic activity of PdBr(2)bis(benzimidazolin-2- ylidene) complexes 2a-d was evaluated in the direct arylation reaction of benzothiazole with bromobenzene derivatives.en_US
dc.description.sponsorshipTechnological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)]; Inonu University Research Fund [2009/13]; Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey [F279]en_US
dc.description.sponsorshipThis work was financially supported by the Technological and Scientific Research Council of Turkey TUBITAK-CNRS (France) [TBAG-U/181 (106T716)], Inonu University Research Fund (I.U.B.A.P: 2009/13) and the Faculty of Arts and Sciences, Ondokuz Mayis University, Turkey, for the use of the Stoe IPDS-II diffractometer (purchased from grant no. F279 of the University Research Fund).en_US
dc.identifier.doi10.1039/b906497b
dc.identifier.endpage7093en_US
dc.identifier.issn1477-9226
dc.identifier.issn1477-9234
dc.identifier.issue35en_US
dc.identifier.pmid20449152en_US
dc.identifier.scopus2-s2.0-69249173045en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage7087en_US
dc.identifier.urihttps://doi.org/10.1039/b906497b
dc.identifier.urihttps://hdl.handle.net/11616/94857
dc.identifier.wosWOS:000269288700027en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.indekslendigikaynakPubMeden_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofDalton Transactionsen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectDirect Ortho Arylationen_US
dc.subjectC-H Bondsen_US
dc.subjectTransition-Metal-Complexesen_US
dc.subjectThin-Film Transistorsen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectAlkene Metathesisen_US
dc.subjectMono-Carbeneen_US
dc.subjectRhodiumen_US
dc.subjectLigandsen_US
dc.subjectAlkenylationen_US
dc.titleSynthesis, characterization and catalytic activity of novel N-heterocyclic carbene-palladium complexesen_US
dc.typeArticleen_US

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