Azo-azomethine based palladium(II) complexes as catalysts for the Suzuki-Miyaura cross-coupling reaction
Küçük Resim Yok
Tarih
2020
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Seven azo-azomethine ligands (2-8) have been synthesized from the reaction of (E)-5-((4-chlorophenyl) diazenyl)-2-hydroxybenzaldehyde with different aniline derivatives. Ligand structures were characterized by the combination of IR, UVeVisible spectroscopy, C-13 NMR, H-1 NMR and elemental analyses. The mononuclear Pd(II) complexes of these azo-azomethine compounds were prepared with sodium tetrachloropalladate(II) and characterized. According to the UVevisible, FTIR, elemental analyze and HRMS data, the Pd (II) complexes 9-15 are formed by the coordination of N, O atoms of the ligands. Solid state structures of 2, 6 and 7 were determined by single crystal X-ray diffraction studies. Also, Pd(II) complexes were used catalysts for Suzuki-Miyaura coupling reactions of phenylboronic acid with aryl bromide in aqueous media. When the catalytic studies were evaluated, it was found that all of the complexes were suitable for the Suzuki-Miyaura cross-coupling reaction. (c) 2020 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Azo-azomethine, Pd(II) complexes, Suzuki-Miyaura coupling, C-C bond Formation
Kaynak
Journal of Molecular Structure
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
Cilt
1216
