Azo-azomethine based palladium(II) complexes as catalysts for the Suzuki-Miyaura cross-coupling reaction

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dc.authoridİKİZ, MESUT/0000-0001-6075-6529
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridEvren, Enes/0000-0002-7571-410X
dc.authorwosidKose, Muhammet/E-8315-2016
dc.authorwosidİKİZ, MESUT/AAC-8067-2021
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorSunbul, Ali Burak
dc.contributor.authorInan, Ayse
dc.contributor.authorKose, Muhammet
dc.contributor.authorEvren, Enes
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorIkiz, Mesut
dc.date.accessioned2024-08-04T20:47:16Z
dc.date.available2024-08-04T20:47:16Z
dc.date.issued2020
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSeven azo-azomethine ligands (2-8) have been synthesized from the reaction of (E)-5-((4-chlorophenyl) diazenyl)-2-hydroxybenzaldehyde with different aniline derivatives. Ligand structures were characterized by the combination of IR, UVeVisible spectroscopy, C-13 NMR, H-1 NMR and elemental analyses. The mononuclear Pd(II) complexes of these azo-azomethine compounds were prepared with sodium tetrachloropalladate(II) and characterized. According to the UVevisible, FTIR, elemental analyze and HRMS data, the Pd (II) complexes 9-15 are formed by the coordination of N, O atoms of the ligands. Solid state structures of 2, 6 and 7 were determined by single crystal X-ray diffraction studies. Also, Pd(II) complexes were used catalysts for Suzuki-Miyaura coupling reactions of phenylboronic acid with aryl bromide in aqueous media. When the catalytic studies were evaluated, it was found that all of the complexes were suitable for the Suzuki-Miyaura cross-coupling reaction. (c) 2020 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipUnit of Coordination of Scientific Research Projects, Kahramanmaras Sutcu Imam University, Kahramanmaras, Turkey [2018/3-29M]en_US
dc.description.sponsorshipThis work was financially supported by the Unit of Coordination of Scientific Research Projects, Kahramanmaras Sutcu Imam University, Kahramanmaras, Turkey (Project no: 2018/3-29M). The authors acknowledge Scientific and Technological Research Application and Research Center, Sinop University, Turkey, for the use of the Bruker D8 QUEST diffractometer and Central Laboratory, METU, Turkey, for the use of the Waters Synapt G1 instrument.en_US
dc.identifier.doi10.1016/j.molstruc.2020.128279
dc.identifier.issn0022-2860
dc.identifier.issn1872-8014
dc.identifier.scopus2-s2.0-85084110774en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.urihttps://doi.org/10.1016/j.molstruc.2020.128279
dc.identifier.urihttps://hdl.handle.net/11616/99266
dc.identifier.volume1216en_US
dc.identifier.wosWOS:000545897700020en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Structureen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAzo-azomethineen_US
dc.subjectPd(II) complexesen_US
dc.subjectSuzuki-Miyaura couplingen_US
dc.subjectC-C bond Formationen_US
dc.titleAzo-azomethine based palladium(II) complexes as catalysts for the Suzuki-Miyaura cross-coupling reactionen_US
dc.typeArticleen_US

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