Rhodium(I) N-heterocyclic carbene complexes as catalysts for the hydrosilylation of aromatic ketones with triethylsilane
Küçük Resim Yok
Tarih
2017
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
New rhodium(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of rhodium dimer [Rh(OMe) COD](2) with two equivalent of 1,3-dialkylimidazolinium chloride salts in tetrahydrofuran. All of the complexes were characterized using elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts in the hydrosilylation of acetophenone derivatives with triethylsilane at 80 degrees C for h. These Rh(I)-NHC complexes showed the good catalytic performance for the hydrosilylation of acetophenone derivatives and the corresponding hydrosilylation products were obtained in moderate to good yields by using 1 mol% of the rhodium complex. (C) 2017 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
Transition-Metal-Complexes, Asymmetric Hydrosilylation, Transfer Hydrogenation, Homogeneous Catalysis, Coupling Reactions, Olefin Metathesis, Rh Complex, Ligands, Palladium, Aldehydes
Kaynak
Inorganica Chimica Acta
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
467
