Rhodium(I) N-heterocyclic carbene complexes as catalysts for the hydrosilylation of aromatic ketones with triethylsilane

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorYigit, Beyhan
dc.contributor.authorYigit, Murat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:43:56Z
dc.date.available2024-08-04T20:43:56Z
dc.date.issued2017
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNew rhodium(I) N-heterocyclic carbene complexes were synthesized in good yields by the reactions of rhodium dimer [Rh(OMe) COD](2) with two equivalent of 1,3-dialkylimidazolinium chloride salts in tetrahydrofuran. All of the complexes were characterized using elemental analysis, H-1 NMR and C-13 NMR spectroscopy. These complexes were used as catalysts in the hydrosilylation of acetophenone derivatives with triethylsilane at 80 degrees C for h. These Rh(I)-NHC complexes showed the good catalytic performance for the hydrosilylation of acetophenone derivatives and the corresponding hydrosilylation products were obtained in moderate to good yields by using 1 mol% of the rhodium complex. (C) 2017 Elsevier B.V. All rights reserved.en_US
dc.description.sponsorshipAdiyaman University Research Fund [FEFMAP/2015-0004]en_US
dc.description.sponsorshipWe thank the Adiyaman University Research Fund (FEFMAP/2015-0004) for financial support of this work.en_US
dc.identifier.doi10.1016/j.ica.2017.07.055
dc.identifier.endpage79en_US
dc.identifier.issn0020-1693
dc.identifier.issn1873-3255
dc.identifier.scopus2-s2.0-85026553317en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage75en_US
dc.identifier.urihttps://doi.org/10.1016/j.ica.2017.07.055
dc.identifier.urihttps://hdl.handle.net/11616/97911
dc.identifier.volume467en_US
dc.identifier.wosWOS:000410686700011en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofInorganica Chimica Actaen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectTransition-Metal-Complexesen_US
dc.subjectAsymmetric Hydrosilylationen_US
dc.subjectTransfer Hydrogenationen_US
dc.subjectHomogeneous Catalysisen_US
dc.subjectCoupling Reactionsen_US
dc.subjectOlefin Metathesisen_US
dc.subjectRh Complexen_US
dc.subjectLigandsen_US
dc.subjectPalladiumen_US
dc.subjectAldehydesen_US
dc.titleRhodium(I) N-heterocyclic carbene complexes as catalysts for the hydrosilylation of aromatic ketones with triethylsilaneen_US
dc.typeArticleen_US

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