Half-sandwich Ru(II) arene complexes bearing benzimidazole ligands for the N-alkylation reaction of aniline with alcohols in a solvent-free medium
Küçük Resim Yok
Tarih
2021
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Royal Soc Chemistry
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
In this article, the direct N-alkylation reactions of amines with alcohol derivatives using the borrowing hydrogen methodology have been investigated. For this purpose, a new series of half-sandwich ruthenium(II) complexes bearing N-coordinated benzimidazole complexes have been synthesized and fully characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopies. Additionally, the structures of the complexes 2a-2e have been characterized by X-ray crystallography. ALL new complexes were investigated for their catalytic activities in the alkylation reaction of amines with alcohol derivatives. It was found that alkylation reactions in a solvent-free medium are efficient and selective.
Açıklama
Anahtar Kelimeler
Ruthenium(Ii) Complexes, Catalytic Efficiency, Hydrogen-Transfer, Secondary-Amines, Discovery, Oxidation, Amination, Imines
Kaynak
New Journal of Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q2
Cilt
45
Sayı
25
