Half-sandwich Ru(II) arene complexes bearing benzimidazole ligands for the N-alkylation reaction of aniline with alcohols in a solvent-free medium

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dc.authoridÖzdemir, Namık/0000-0003-3371-9874
dc.authoridGurbuz, Nevin/0000-0003-3201-3597
dc.authoridOzdemir, Ismail/0000-0001-6325-0216
dc.authoridIspir, Esin/0000-0002-7245-9377
dc.authorwosidÖzdemir, Namık/J-6434-2015
dc.authorwosidGurbuz, Nevin/A-3069-2016
dc.contributor.authorCicek, Metin
dc.contributor.authorGurbuz, Nevin
dc.contributor.authorOzdemir, Namik
dc.contributor.authorOzdemir, Ismail
dc.contributor.authorIspir, Esin
dc.date.accessioned2024-08-04T20:50:23Z
dc.date.available2024-08-04T20:50:23Z
dc.date.issued2021
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this article, the direct N-alkylation reactions of amines with alcohol derivatives using the borrowing hydrogen methodology have been investigated. For this purpose, a new series of half-sandwich ruthenium(II) complexes bearing N-coordinated benzimidazole complexes have been synthesized and fully characterized by FT-IR, H-1 NMR and C-13 NMR spectroscopies. Additionally, the structures of the complexes 2a-2e have been characterized by X-ray crystallography. ALL new complexes were investigated for their catalytic activities in the alkylation reaction of amines with alcohol derivatives. It was found that alkylation reactions in a solvent-free medium are efficient and selective.en_US
dc.description.sponsorshipScientific Research Projects Unit of Ondokuz Mays University [PYO.FEN.1906.19.001]en_US
dc.description.sponsorshipThis study was supported by Scientific Research Projects Unit of Ondokuz Mays University (Project No. PYO.FEN.1906.19.001).en_US
dc.identifier.doi10.1039/d1nj01539g
dc.identifier.endpage11085en_US
dc.identifier.issn1144-0546
dc.identifier.issn1369-9261
dc.identifier.issue25en_US
dc.identifier.scopus2-s2.0-85108881742en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage11075en_US
dc.identifier.urihttps://doi.org/10.1039/d1nj01539g
dc.identifier.urihttps://hdl.handle.net/11616/100009
dc.identifier.volume45en_US
dc.identifier.wosWOS:000658013400001en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherRoyal Soc Chemistryen_US
dc.relation.ispartofNew Journal of Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectRuthenium(Ii) Complexesen_US
dc.subjectCatalytic Efficiencyen_US
dc.subjectHydrogen-Transferen_US
dc.subjectSecondary-Aminesen_US
dc.subjectDiscoveryen_US
dc.subjectOxidationen_US
dc.subjectAminationen_US
dc.subjectIminesen_US
dc.titleHalf-sandwich Ru(II) arene complexes bearing benzimidazole ligands for the N-alkylation reaction of aniline with alcohols in a solvent-free mediumen_US
dc.typeArticleen_US

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