Copper Cementation with Zinc Recovered from Spent Zinc-Carbon Batteries and Dissolution of Cement Copper in Hydrochloric Acid Solutions

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dc.authoridDemirkıran, Nizamettin/0000-0001-9021-2477
dc.authorwosidDemirkıran, Nizamettin/ABF-2443-2020
dc.contributor.authorDemirkiran, Nizamettin
dc.date.accessioned2024-08-04T20:37:42Z
dc.date.available2024-08-04T20:37:42Z
dc.date.issued2013
dc.departmentİnönü Üniversitesien_US
dc.description.abstractIn this study, the usability of waste zinc obtained from spent zinc carbon batteries for copper cementation was examined. The effects of the initial concentration of copper ions, rotation speed of the zinc plate, initial pH of solution, and reaction temperature on copper cementation were investigated. It was determined that the cementation rate increased with increasing concentration of copper ions, rotation speed, reaction temperature, and initial pH of solution. It was found that the cementation reaction followed first-order kinetics and was controlled by diffusion. Copper powder produced by cementation was characterized using X-ray diffraction and scanning electron microscopy techniques. The dissolution of cement copper in hydrochloric acid solution was determined for the purpose of the production of copper(II) oxychloride. The effects of acid concentration, temperature, and stirring speed on the dissolution of cement copper were investigated. It was observed that the dissolution of copper powder increased with an increase in acid concentration, stirring speed, and temperature.en_US
dc.identifier.doi10.1021/ie400438b
dc.identifier.endpage8166en_US
dc.identifier.issn0888-5885
dc.identifier.issue24en_US
dc.identifier.scopus2-s2.0-84879390904en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage8157en_US
dc.identifier.urihttps://doi.org/10.1021/ie400438b
dc.identifier.urihttps://hdl.handle.net/11616/96107
dc.identifier.volume52en_US
dc.identifier.wosWOS:000320898700007en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherAmer Chemical Socen_US
dc.relation.ispartofIndustrial & Engineering Chemistry Researchen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectAnode-Support Systemen_US
dc.subjectLeaching Kineticsen_US
dc.subjectSulfate-Solutionsen_US
dc.subjectMetallic Copperen_US
dc.subjectAluminum Discen_US
dc.subjectMalachiteen_US
dc.subjectNanoparticlesen_US
dc.subjectChlorideen_US
dc.subjectNickelen_US
dc.subjectCobalten_US
dc.titleCopper Cementation with Zinc Recovered from Spent Zinc-Carbon Batteries and Dissolution of Cement Copper in Hydrochloric Acid Solutionsen_US
dc.typeArticleen_US

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