Synthesis of cis- and trans-dichloro(dimethylphenylphosphine) x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral and structural characterization
Küçük Resim Yok
Tarih
1998
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier Science Sa
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Interaction of [{Pt(mu-Cl)Cl(PMe2Ph)}(2)] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R = Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N = CH(Me)CH2CH2CH2}] trans-complex 2 isomerizes to give thermody-namically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed. (C) 1998 Elsevier Science S.A. All rights reserved.
Açıklama
Anahtar Kelimeler
tetrahydropyrimidine complexes, platinum(II), trans-influences, cis-trans-isomerizations
Kaynak
Journal of Organometallic Chemistry
WoS Q Değeri
Q2
Scopus Q Değeri
Q3
Cilt
561
Sayı
1-2
