Synthesis of cis- and trans-dichloro(dimethylphenylphosphine) x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral and structural characterization

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dc.authoridTahir, Muhammad Nawaz/0000-0002-6815-9806
dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authorwosidTahir, Muhammad Nawaz/HPB-5726-2023
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorCetinkaya, B
dc.contributor.authorOzdemir, I
dc.contributor.authorTahir, MN
dc.contributor.authorUlku, D
dc.date.accessioned2024-08-04T20:11:46Z
dc.date.available2024-08-04T20:11:46Z
dc.date.issued1998
dc.departmentİnönü Üniversitesien_US
dc.description.abstractInteraction of [{Pt(mu-Cl)Cl(PMe2Ph)}(2)] with 1-methyl-1,4,5,6-tetrahydropyrimidine, L (R = Me), in boiling toluene produced a mixture of cis- and trans- isomers of [PtCl2(PMe2Ph){N = CH(Me)CH2CH2CH2}] trans-complex 2 isomerizes to give thermody-namically more stable corresponding cis-complex 1 in boiling ethanol. Spectroscopic and X-ray diffraction data permit generalizations about cis- and trans- isomeric pairs to be made. In addition, the trans influence of the ligand L is reliably assessed. (C) 1998 Elsevier Science S.A. All rights reserved.en_US
dc.identifier.doi10.1016/S0022-328X(98)00471-9
dc.identifier.endpage11en_US
dc.identifier.issn0022-328X
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-0001900538en_US
dc.identifier.scopusqualityQ3en_US
dc.identifier.startpage7en_US
dc.identifier.urihttps://doi.org/10.1016/S0022-328X(98)00471-9
dc.identifier.urihttps://hdl.handle.net/11616/92985
dc.identifier.volume561en_US
dc.identifier.wosWOS:000074670300002en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevier Science Saen_US
dc.relation.ispartofJournal of Organometallic Chemistryen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjecttetrahydropyrimidine complexesen_US
dc.subjectplatinum(II)en_US
dc.subjecttrans-influencesen_US
dc.subjectcis-trans-isomerizationsen_US
dc.titleSynthesis of cis- and trans-dichloro(dimethylphenylphosphine) x-(1-methyl-1,4,5,6-tetrahydropyrimidine)platinum(II) and their spectral and structural characterizationen_US
dc.typeArticleen_US

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