Novel N-heterocyclic-carbene-rhodium complexes as hydrosilylation catalysts
Küçük Resim Yok
Tarih
2005
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Elsevier
Erişim Hakkı
info:eu-repo/semantics/closedAccess
Özet
Novel rhodium-1,3-dialkylperhydrobenzimidazolin-2-ylidene (2a,b) and 1,3-dialkylimidazolin-2-ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkylperhydrobenzimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) to give the corresponding silylethers in good yields (63-99%). (c) 2005 Elsevier B.V. All rights reserved.
Açıklama
Anahtar Kelimeler
perhydrobenzimidazolin-2-ylidene, imidazolin-2-ylidene N-heterocyclic carbene, hydrosilylation, rhodium
Kaynak
Journal of Molecular Catalysis A-Chemical
WoS Q Değeri
Q2
Scopus Q Değeri
N/A
Cilt
241
Sayı
1-2
