Novel N-heterocyclic-carbene-rhodium complexes as hydrosilylation catalysts

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dc.authoridÖzdemir, İsmail/0000-0001-6325-0216
dc.authoridCetinkaya, Bekir/0000-0002-4551-8650
dc.authorwosidÖzdemir, İsmail/ABI-5192-2020
dc.contributor.authorYigit, M
dc.contributor.authorÖzdemir, I
dc.contributor.authorÇetinkaya, B
dc.contributor.authorÇetinkaya, E
dc.date.accessioned2024-08-04T20:15:02Z
dc.date.available2024-08-04T20:15:02Z
dc.date.issued2005
dc.departmentİnönü Üniversitesien_US
dc.description.abstractNovel rhodium-1,3-dialkylperhydrobenzimidazolin-2-ylidene (2a,b) and 1,3-dialkylimidazolin-2-ylidene complexes (4a,b) have been prepared and characterized by C, H, N analysis, H-1 NMR and C-13 NMR. Triethylsilane reacts with acetophenone derivatives in the presence of catalytic amount of the new rhodium(I)-carbene complexes, RhCl(COD)(1,3-dialkylperhydrobenzimidazolin-2-ylidene) or RhCl(COD)(1,3-dialkylimidazolin-2-ylidene) to give the corresponding silylethers in good yields (63-99%). (c) 2005 Elsevier B.V. All rights reserved.en_US
dc.identifier.doi10.1016/j.molcata.2005.07.012
dc.identifier.endpage92en_US
dc.identifier.issn1381-1169
dc.identifier.issn1873-314X
dc.identifier.issue1-2en_US
dc.identifier.scopus2-s2.0-25844526377en_US
dc.identifier.scopusqualityN/Aen_US
dc.identifier.startpage88en_US
dc.identifier.urihttps://doi.org/10.1016/j.molcata.2005.07.012
dc.identifier.urihttps://hdl.handle.net/11616/94124
dc.identifier.volume241en_US
dc.identifier.wosWOS:000232712200012en_US
dc.identifier.wosqualityQ2en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofJournal of Molecular Catalysis A-Chemicalen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectperhydrobenzimidazolin-2-ylideneen_US
dc.subjectimidazolin-2-ylidene N-heterocyclic carbeneen_US
dc.subjecthydrosilylationen_US
dc.subjectrhodiumen_US
dc.titleNovel N-heterocyclic-carbene-rhodium complexes as hydrosilylation catalystsen_US
dc.typeArticleen_US

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