Palladium N-Heterocyclic Carbene Pre-catalysts Bearing Different Ancillary Ligands for the Buchwald-Hartwig Amination of Cyclic Secondary Amines with Aryl Chlorides

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dc.authoridKALOGLU, MURAT/0000-0002-2770-5532
dc.authorwosidOZDEMIR, ISMAIL/KVY-3420-2024
dc.contributor.authorKaloglu, Murat
dc.contributor.authorOzdemir, Ismail
dc.date.accessioned2024-08-04T20:54:37Z
dc.date.available2024-08-04T20:54:37Z
dc.date.issued2024
dc.departmentİnönü Üniversitesien_US
dc.description.abstractSix novel palladium N-heterocyclic carbene complexes bearing different ancillary ligands such as pyridine, 1-methylimidazole, 4,5-dimethylthiazole and 3-bromoquinoline have been successfully prepared in a one-step process. These complexes were used as pre-catalysts in the Buchwald-Hartwig amination of cyclic secondary amines with aryl chlorides. A range of cyclic secondary amines were tolerated to a wide variety of aryl chlorides in presence of 1 mol% catalyst loading under mild conditions. Under the tested reaction conditions, the expected N-arylamines were obtained in moderate to high yields. The results showed that these novel palladium complexes are effective catalysts for the Buchwald-Hartwig amination.Graphic Abstracten_US
dc.description.sponsorshipInonu University (I.U.B.A.P. Project) [FBA-2022-2844]en_US
dc.description.sponsorshipSupport of Inonu University Research Fund (I.U.B.A.P. Project No: FBA-2022-2844) is gratefully acknowledged.en_US
dc.identifier.doi10.1007/s10562-023-04432-w
dc.identifier.endpage1494en_US
dc.identifier.issn1011-372X
dc.identifier.issn1572-879X
dc.identifier.issue4en_US
dc.identifier.scopus2-s2.0-85167341840en_US
dc.identifier.scopusqualityQ2en_US
dc.identifier.startpage1479en_US
dc.identifier.urihttps://doi.org/10.1007/s10562-023-04432-w
dc.identifier.urihttps://hdl.handle.net/11616/101505
dc.identifier.volume154en_US
dc.identifier.wosWOS:001045120700001en_US
dc.identifier.wosqualityQ3en_US
dc.indekslendigikaynakWeb of Scienceen_US
dc.indekslendigikaynakScopusen_US
dc.language.isoenen_US
dc.publisherSpringeren_US
dc.relation.ispartofCatalysis Lettersen_US
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/closedAccessen_US
dc.subjectPalladiumen_US
dc.subjectN-Heterocyclic carbeneen_US
dc.subjectCyclic secondary aminesen_US
dc.subjectBuchwald-Hartwig aminationen_US
dc.titlePalladium N-Heterocyclic Carbene Pre-catalysts Bearing Different Ancillary Ligands for the Buchwald-Hartwig Amination of Cyclic Secondary Amines with Aryl Chloridesen_US
dc.typeArticleen_US

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